TY - JOUR

T1 - Development of high-entropy shape-memory alloys

T2 - structure and properties

AU - Firstov, G. S.

AU - Koval, Yu M.

AU - Filatova, V. S.

AU - Odnosum, V. V.

AU - Gerstein, G.

AU - Maier, H. J.

N1 - Funding Information: Acknowledgements. Financial support by the fundamental Project

PY - 2023/12/12

Y1 - 2023/12/12

N2 - Amongst functional materials, shape-memory alloys occupy a special position. After their discovery these alloys attracted substantial attention because of the possibility to restore significant deformation amounts under certain stress–temperature conditions due to the martensitic diffusionless phase transformation involved. It was possible to exploit not only so-called ‘shape-memory’ effect, but also superelasticity and high damping capacity. Over the years, more than 10 000 patents on shape-memory alloys were filed, appreciating not only the possibility to exploit the energy transformation to ensure the response (feedback) at the change in independent thermodynamic parameters (temperature, stress, pressure, electric or magnetic field, etc.), but the significant work output as well. The envisaged shape memory components covered applications in the automotive, aerospace, machine building and civil construction industries. Unfortunately, structural and functional fatigue restricted successful business application mostly to the medical sector, with the Nitinol shape-memory alloy dominating applications such as different implants, stents or cardiovascular valves. Emerging high-entropy shape-memory alloys can be considered as a chance to overcome the fatigue problems of today’s shape-memory alloys due to their specific structure that ensures superior resistance to irreversible plastic deformation.

AB - Amongst functional materials, shape-memory alloys occupy a special position. After their discovery these alloys attracted substantial attention because of the possibility to restore significant deformation amounts under certain stress–temperature conditions due to the martensitic diffusionless phase transformation involved. It was possible to exploit not only so-called ‘shape-memory’ effect, but also superelasticity and high damping capacity. Over the years, more than 10 000 patents on shape-memory alloys were filed, appreciating not only the possibility to exploit the energy transformation to ensure the response (feedback) at the change in independent thermodynamic parameters (temperature, stress, pressure, electric or magnetic field, etc.), but the significant work output as well. The envisaged shape memory components covered applications in the automotive, aerospace, machine building and civil construction industries. Unfortunately, structural and functional fatigue restricted successful business application mostly to the medical sector, with the Nitinol shape-memory alloy dominating applications such as different implants, stents or cardiovascular valves. Emerging high-entropy shape-memory alloys can be considered as a chance to overcome the fatigue problems of today’s shape-memory alloys due to their specific structure that ensures superior resistance to irreversible plastic deformation.

KW - high-entropy shape-memory alloys

KW - martensitic transformation

KW - mechanical properties

KW - multiple principal element intermetallic compounds

KW - shape memory and related phenomena

KW - structure

UR - http://www.scopus.com/inward/record.url?scp=85182826510&partnerID=8YFLogxK

U2 - 10.15407/ufm.24.04.819

DO - 10.15407/ufm.24.04.819

M3 - Article

AN - SCOPUS:85182826510

VL - 24

SP - 819

EP - 837

JO - Progress in Physics of Metals

JF - Progress in Physics of Metals

SN - 1608-1021

IS - 4

ER -