Details
| Originalsprache | Englisch |
|---|---|
| Aufsatznummer | 013301 |
| Seitenumfang | 4 |
| Fachzeitschrift | Applied Physics Letters |
| Jahrgang | 113 |
| Ausgabenummer | 1 |
| Publikationsstatus | Veröffentlicht - 2 Juli 2018 |
Abstract
Metal-halide perovskites are promising materials for applications like lasers and solar cells. In this work, we show the importance of an accurate determination of the source material parameters (acoustic impedance ratio and density) for thermal co-evaporation of soft materials like perovskites. We use here methylammonium iodide and lead(II)iodide for the exemplary deposition of methylammoniumlead(II)triiodide. We measure the thickness of the deposited layers by scanning electron microscopy cross sections and monitor the frequency change of the quartz crystal microbalances. We use a model with a one-dimensional acoustical composite resonator for the correct determination of the acoustic impedance ratio, resulting in values of 0.025 ± 0.002 for methylammonium iodide and of 0.11 ± 0.01 for lead(II)iodide. We use the resulting material parameters to deposit a layer of crystalline methylammonium lead triiodide with an accurately controlled stoichiometry of MAPbIx with x = 3.2 ± 0.2. We show the impact assuming false acoustic impedance ratios by simulating the actual evaporation rates of the source materials. We show that the ratio of the evaporation rates changes significantly during the deposition process. This results in a strong stoichiometry gradient in the perovskite layer and a mismatch in the average stoichiometry for a typical absorber thickness of 600 nm.
ASJC Scopus Sachgebiete
- Physik und Astronomie (insg.)
- Physik und Astronomie (sonstige)
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in: Applied Physics Letters, Jahrgang 113, Nr. 1, 013301, 02.07.2018.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Determination and influence evaluation of the acoustic impedance ratio for thermal co-evaporation
AU - Wolter, Sascha Jozsef
AU - Steckenreiter, Verena
AU - Tatarzyn, Marta Christine
AU - Wietler, Tobias
AU - Niepelt, Raphael
AU - Kajari-Schröder, Sarah
N1 - Funding information: This work was performed within the framework of the EASi research project with funding from the Federal Ministry for Economic Affairs and Energy (FKZ0324040).
PY - 2018/7/2
Y1 - 2018/7/2
N2 - Metal-halide perovskites are promising materials for applications like lasers and solar cells. In this work, we show the importance of an accurate determination of the source material parameters (acoustic impedance ratio and density) for thermal co-evaporation of soft materials like perovskites. We use here methylammonium iodide and lead(II)iodide for the exemplary deposition of methylammoniumlead(II)triiodide. We measure the thickness of the deposited layers by scanning electron microscopy cross sections and monitor the frequency change of the quartz crystal microbalances. We use a model with a one-dimensional acoustical composite resonator for the correct determination of the acoustic impedance ratio, resulting in values of 0.025 ± 0.002 for methylammonium iodide and of 0.11 ± 0.01 for lead(II)iodide. We use the resulting material parameters to deposit a layer of crystalline methylammonium lead triiodide with an accurately controlled stoichiometry of MAPbIx with x = 3.2 ± 0.2. We show the impact assuming false acoustic impedance ratios by simulating the actual evaporation rates of the source materials. We show that the ratio of the evaporation rates changes significantly during the deposition process. This results in a strong stoichiometry gradient in the perovskite layer and a mismatch in the average stoichiometry for a typical absorber thickness of 600 nm.
AB - Metal-halide perovskites are promising materials for applications like lasers and solar cells. In this work, we show the importance of an accurate determination of the source material parameters (acoustic impedance ratio and density) for thermal co-evaporation of soft materials like perovskites. We use here methylammonium iodide and lead(II)iodide for the exemplary deposition of methylammoniumlead(II)triiodide. We measure the thickness of the deposited layers by scanning electron microscopy cross sections and monitor the frequency change of the quartz crystal microbalances. We use a model with a one-dimensional acoustical composite resonator for the correct determination of the acoustic impedance ratio, resulting in values of 0.025 ± 0.002 for methylammonium iodide and of 0.11 ± 0.01 for lead(II)iodide. We use the resulting material parameters to deposit a layer of crystalline methylammonium lead triiodide with an accurately controlled stoichiometry of MAPbIx with x = 3.2 ± 0.2. We show the impact assuming false acoustic impedance ratios by simulating the actual evaporation rates of the source materials. We show that the ratio of the evaporation rates changes significantly during the deposition process. This results in a strong stoichiometry gradient in the perovskite layer and a mismatch in the average stoichiometry for a typical absorber thickness of 600 nm.
UR - http://www.scopus.com/inward/record.url?scp=85049750398&partnerID=8YFLogxK
U2 - 10.1063/1.5037403
DO - 10.1063/1.5037403
M3 - Article
AN - SCOPUS:85049750398
VL - 113
JO - Applied Physics Letters
JF - Applied Physics Letters
SN - 0003-6951
IS - 1
M1 - 013301
ER -