Cyano-bridged dinuclear iron complexes in different oxidation states

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Autoren

  • Shaohua Gou
  • Franz Renz
  • Yutaka Fukuda
  • Wolfgang Linert

Organisationseinheiten

Externe Organisationen

  • Technische Universität Wien (TUW)
  • Nanjing University
  • Ochanomizu University
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)95-100
Seitenumfang6
FachzeitschriftInorganica chimica acta
Jahrgang287
Ausgabenummer1
PublikationsstatusVeröffentlicht - 2 Apr. 1999

Abstract

Two dinuclear iron complexes, bridged via cyano groups, containing units of [Fe(phen)2(CN)2]n (n=0 or +1) and a chelating ligand, the nitrilotriacetic acid anion, have been synthesised. These compounds, containing iron atoms in different and/or the same oxidation states [Fe(II)/Fe(III) (1); Fe(III)/Fe(III) (2)] were characterised by elemental analyses, IR and UV spectra, TGA and DSC thermograms. Mössbauer spectra and magnetic susceptibility of complex 1 were investigated and discussed.

ASJC Scopus Sachgebiete

Zitieren

Cyano-bridged dinuclear iron complexes in different oxidation states. / Gou, Shaohua; Renz, Franz; Fukuda, Yutaka et al.
in: Inorganica chimica acta, Jahrgang 287, Nr. 1, 02.04.1999, S. 95-100.

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Gou S, Renz F, Fukuda Y, Linert W. Cyano-bridged dinuclear iron complexes in different oxidation states. Inorganica chimica acta. 1999 Apr 2;287(1):95-100. doi: 10.1016/S0020-1693(99)00003-1
Gou, Shaohua ; Renz, Franz ; Fukuda, Yutaka et al. / Cyano-bridged dinuclear iron complexes in different oxidation states. in: Inorganica chimica acta. 1999 ; Jahrgang 287, Nr. 1. S. 95-100.
Download
@article{d264570ceb0f496a852f26702dfe2fdc,
title = "Cyano-bridged dinuclear iron complexes in different oxidation states",
abstract = "Two dinuclear iron complexes, bridged via cyano groups, containing units of [Fe(phen)2(CN)2]n (n=0 or +1) and a chelating ligand, the nitrilotriacetic acid anion, have been synthesised. These compounds, containing iron atoms in different and/or the same oxidation states [Fe(II)/Fe(III) (1); Fe(III)/Fe(III) (2)] were characterised by elemental analyses, IR and UV spectra, TGA and DSC thermograms. M{\"o}ssbauer spectra and magnetic susceptibility of complex 1 were investigated and discussed.",
keywords = "Cyano-bridged complexes, Dinuclear complexes, Iron complexes",
author = "Shaohua Gou and Franz Renz and Yutaka Fukuda and Wolfgang Linert",
note = "Funding Information: Acknowledgment for financial support is due to the Fonds zur F{\"o}rderung der Wissenschaflichen Forschung in {\"O}sterreich (project 11218), and to the Training and Mobility of Researchers Network (TMR) project Thermal and Optical Spin State Switching (TOSS) supported by the European Community under the Contract number ERB-FMRX-CT98-0199. Grants in aid for Scientific Research from the Ministry of Education, Science and Culture in Japan (nos. 07454173, 08220222, and 08554026) are thankfully acknowledged. S.G. is grateful to the {\"O}AD ({\"O}sterreichischer Akademischer Austauschdienst) for a research scholarship. We would also like to thank G. Wiesinger of the Institute of Experimental Physics at TU-Wien for his assistance in the measurement of the M{\"o}ssbauer spectrum and R. Boca (TU-Bratislava, Slovakia) for assistance with the magnetic measurements.",
year = "1999",
month = apr,
day = "2",
doi = "10.1016/S0020-1693(99)00003-1",
language = "English",
volume = "287",
pages = "95--100",
journal = "Inorganica chimica acta",
issn = "0020-1693",
publisher = "Elsevier BV",
number = "1",

}

Download

TY - JOUR

T1 - Cyano-bridged dinuclear iron complexes in different oxidation states

AU - Gou, Shaohua

AU - Renz, Franz

AU - Fukuda, Yutaka

AU - Linert, Wolfgang

N1 - Funding Information: Acknowledgment for financial support is due to the Fonds zur Förderung der Wissenschaflichen Forschung in Österreich (project 11218), and to the Training and Mobility of Researchers Network (TMR) project Thermal and Optical Spin State Switching (TOSS) supported by the European Community under the Contract number ERB-FMRX-CT98-0199. Grants in aid for Scientific Research from the Ministry of Education, Science and Culture in Japan (nos. 07454173, 08220222, and 08554026) are thankfully acknowledged. S.G. is grateful to the ÖAD (Österreichischer Akademischer Austauschdienst) for a research scholarship. We would also like to thank G. Wiesinger of the Institute of Experimental Physics at TU-Wien for his assistance in the measurement of the Mössbauer spectrum and R. Boca (TU-Bratislava, Slovakia) for assistance with the magnetic measurements.

PY - 1999/4/2

Y1 - 1999/4/2

N2 - Two dinuclear iron complexes, bridged via cyano groups, containing units of [Fe(phen)2(CN)2]n (n=0 or +1) and a chelating ligand, the nitrilotriacetic acid anion, have been synthesised. These compounds, containing iron atoms in different and/or the same oxidation states [Fe(II)/Fe(III) (1); Fe(III)/Fe(III) (2)] were characterised by elemental analyses, IR and UV spectra, TGA and DSC thermograms. Mössbauer spectra and magnetic susceptibility of complex 1 were investigated and discussed.

AB - Two dinuclear iron complexes, bridged via cyano groups, containing units of [Fe(phen)2(CN)2]n (n=0 or +1) and a chelating ligand, the nitrilotriacetic acid anion, have been synthesised. These compounds, containing iron atoms in different and/or the same oxidation states [Fe(II)/Fe(III) (1); Fe(III)/Fe(III) (2)] were characterised by elemental analyses, IR and UV spectra, TGA and DSC thermograms. Mössbauer spectra and magnetic susceptibility of complex 1 were investigated and discussed.

KW - Cyano-bridged complexes

KW - Dinuclear complexes

KW - Iron complexes

UR - http://www.scopus.com/inward/record.url?scp=0003037368&partnerID=8YFLogxK

U2 - 10.1016/S0020-1693(99)00003-1

DO - 10.1016/S0020-1693(99)00003-1

M3 - Article

AN - SCOPUS:0003037368

VL - 287

SP - 95

EP - 100

JO - Inorganica chimica acta

JF - Inorganica chimica acta

SN - 0020-1693

IS - 1

ER -