Correlation of multiple scattering features in XANES spectra of Al and Si K edges to the AlOSi bond angle in aluminosilicate sodalites: An empirical study

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • M. Fröba
  • J. Wong
  • P. Behrens
  • P. Sieger
  • M. Rowen
  • T. Tanaka
  • Z. Rek
  • J. Felsche

Externe Organisationen

  • Lawrence Livermore National Laboratory
  • Universität Konstanz
  • Stanford University
  • National Institute for Materials Science Tsukuba
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Details

OriginalspracheEnglisch
Seiten (von - bis)65-67
Seitenumfang3
FachzeitschriftPhysica B: Physics of Condensed Matter
Jahrgang208-209
AusgabenummerC
PublikationsstatusVeröffentlicht - 1 März 1995
Extern publiziertJa

Abstract

Using a YB66 monochromator X-ray absorption measurements were carried out at the Al K and Si K absorption edges of a series of aluminosilicate sodalites. The AlOSi bridging angle of the selected sodalites varies from 138° to 148° and the structure of the XANES with its different multiple scattering (MS) features shows a strong angular dependence. Increasing the angle results in a decrease of the MS intensities. This dependence is especially pronounced at the Al K edges which contain a couple of separated well-resolved peaks whereas the corresponding features at the Si K edges are smeared out due to a strong overlapping of the peaks.

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Correlation of multiple scattering features in XANES spectra of Al and Si K edges to the AlOSi bond angle in aluminosilicate sodalites: An empirical study. / Fröba, M.; Wong, J.; Behrens, P. et al.
in: Physica B: Physics of Condensed Matter, Jahrgang 208-209, Nr. C, 01.03.1995, S. 65-67.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Fröba M, Wong J, Behrens P, Sieger P, Rowen M, Tanaka T et al. Correlation of multiple scattering features in XANES spectra of Al and Si K edges to the AlOSi bond angle in aluminosilicate sodalites: An empirical study. Physica B: Physics of Condensed Matter. 1995 Mär 1;208-209(C):65-67. doi: 10.1016/0921-4526(94)00820-L
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title = "Correlation of multiple scattering features in XANES spectra of Al and Si K edges to the AlOSi bond angle in aluminosilicate sodalites: An empirical study",
abstract = "Using a YB66 monochromator X-ray absorption measurements were carried out at the Al K and Si K absorption edges of a series of aluminosilicate sodalites. The AlOSi bridging angle of the selected sodalites varies from 138° to 148° and the structure of the XANES with its different multiple scattering (MS) features shows a strong angular dependence. Increasing the angle results in a decrease of the MS intensities. This dependence is especially pronounced at the Al K edges which contain a couple of separated well-resolved peaks whereas the corresponding features at the Si K edges are smeared out due to a strong overlapping of the peaks.",
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T1 - Correlation of multiple scattering features in XANES spectra of Al and Si K edges to the AlOSi bond angle in aluminosilicate sodalites

T2 - An empirical study

AU - Fröba, M.

AU - Wong, J.

AU - Behrens, P.

AU - Sieger, P.

AU - Rowen, M.

AU - Tanaka, T.

AU - Rek, Z.

AU - Felsche, J.

N1 - Funding information: The work was performed under the auspices of the US Department of Energy (DOE) by the Lawrence Livermore National Laboratory under contract number W-7405-ENG-48. The measurements were carried at SSRL which is supported by the Chemical Sciences Division of the DOE. M.F. thanks the Alexander von Humboldt Foundation for a Feodor Lynen Research Fellowship.

PY - 1995/3/1

Y1 - 1995/3/1

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AB - Using a YB66 monochromator X-ray absorption measurements were carried out at the Al K and Si K absorption edges of a series of aluminosilicate sodalites. The AlOSi bridging angle of the selected sodalites varies from 138° to 148° and the structure of the XANES with its different multiple scattering (MS) features shows a strong angular dependence. Increasing the angle results in a decrease of the MS intensities. This dependence is especially pronounced at the Al K edges which contain a couple of separated well-resolved peaks whereas the corresponding features at the Si K edges are smeared out due to a strong overlapping of the peaks.

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