Controlled transformations in transparent conducting films fabricated from highly stable hydrophilic dispersions of SWNTs through surface charge manipulation and acid treatment conditions

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OriginalspracheEnglisch
Seiten (von - bis)1447-1455
Seitenumfang9
FachzeitschriftPhysica Status Solidi (A) Applications and Materials Science
Jahrgang213
Ausgabenummer6
PublikationsstatusVeröffentlicht - 8 März 2016

Abstract

Single wall carbon nanotubes (SWNTs) are considered to be one of the potential candidates for the production of transparent conducting films (TCFs), which can be used in many applications, e.g., touch panels, displays, and polymer solar cells. However, for making optimum usage of the superior properties of SWNTs, a better understanding on the processing and fabrication of thin films is essential. In this work, the effects of the purification conditions of SWNTs, the stability of their dispersions as a function of pH, and the performance of TCFs fabricated from dispersions of different pH are studied. The figure of merit σdcoc for such films can be increased by factor of 2 when the pH of the SWNT dispersion is increased, i.e., the optical and electrical performance is improved significantly. We also report the surface charge-manipulated transformations in transparent conducting films fabricated from SWNT dispersions of different pH values.

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Controlled transformations in transparent conducting films fabricated from highly stable hydrophilic dispersions of SWNTs through surface charge manipulation and acid treatment conditions. / Anto, Bibin T.; Schwarz, Hans Christoph; Eiden, Stefanie et al.
in: Physica Status Solidi (A) Applications and Materials Science, Jahrgang 213, Nr. 6, 08.03.2016, S. 1447-1455.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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abstract = "Single wall carbon nanotubes (SWNTs) are considered to be one of the potential candidates for the production of transparent conducting films (TCFs), which can be used in many applications, e.g., touch panels, displays, and polymer solar cells. However, for making optimum usage of the superior properties of SWNTs, a better understanding on the processing and fabrication of thin films is essential. In this work, the effects of the purification conditions of SWNTs, the stability of their dispersions as a function of pH, and the performance of TCFs fabricated from dispersions of different pH are studied. The figure of merit σdc/σoc for such films can be increased by factor of 2 when the pH of the SWNT dispersion is increased, i.e., the optical and electrical performance is improved significantly. We also report the surface charge-manipulated transformations in transparent conducting films fabricated from SWNT dispersions of different pH values.",
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AU - Behrens, Peter

N1 - Funding information: We thank the European Commission for the funding from Seventh Framework Programme (FP7/2007-2013) under grant agreement no. 238363. We sincerely thank Jens Sicking and Wolfgang Weiner for their extensive support during XPS and Raman spectroscopic measurements, respectively. HCS and PB acknowledge funding from the Cluster of Excellence Hearing4all.

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N2 - Single wall carbon nanotubes (SWNTs) are considered to be one of the potential candidates for the production of transparent conducting films (TCFs), which can be used in many applications, e.g., touch panels, displays, and polymer solar cells. However, for making optimum usage of the superior properties of SWNTs, a better understanding on the processing and fabrication of thin films is essential. In this work, the effects of the purification conditions of SWNTs, the stability of their dispersions as a function of pH, and the performance of TCFs fabricated from dispersions of different pH are studied. The figure of merit σdc/σoc for such films can be increased by factor of 2 when the pH of the SWNT dispersion is increased, i.e., the optical and electrical performance is improved significantly. We also report the surface charge-manipulated transformations in transparent conducting films fabricated from SWNT dispersions of different pH values.

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