Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 947-952 |
| Seitenumfang | 6 |
| Fachzeitschrift | Journal of crystal growth |
| Jahrgang | 312 |
| Ausgabenummer | 7 |
| Frühes Online-Datum | 11 Jan. 2010 |
| Publikationsstatus | Elektronisch veröffentlicht (E-Pub) - 11 Jan. 2010 |
Abstract
Micro-sized ZnO crystals with different shapes have been successfully synthesized by a simple solvothermal reaction of zinc nitrate hexahydrate and julolidine in N, N-dimethylformamide (DMF). The growth of ZnO crystals with tunable shape was controlled through a suppressed crystal growth of the (0 0 0 1) facets along c-axis direction due to the julolidine compound selective adsorbing on the positive (0 0 0 1) facets by coordinating Zn cations with its N atoms. Systematic reactions in the presence of different amounts of DMF were conducted to control the formation of various well-shaped ZnO crystals. The selective adsorption of julolidine on the growing facets resulted in the formation of grooved hexagonal disks, hexagonal disks, hexagonal pyramids, and hexagonal rods.
ASJC Scopus Sachgebiete
- Physik und Astronomie (insg.)
- Physik der kondensierten Materie
- Chemie (insg.)
- Anorganische Chemie
- Werkstoffwissenschaften (insg.)
- Werkstoffchemie
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in: Journal of crystal growth, Jahrgang 312, Nr. 7, 11.01.2010, S. 947-952.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Controlled growth of zinc oxide crystals with tunable shape
AU - Huang, Aisheng
AU - Caro, Jürgen
PY - 2010/1/11
Y1 - 2010/1/11
N2 - Micro-sized ZnO crystals with different shapes have been successfully synthesized by a simple solvothermal reaction of zinc nitrate hexahydrate and julolidine in N, N-dimethylformamide (DMF). The growth of ZnO crystals with tunable shape was controlled through a suppressed crystal growth of the (0 0 0 1) facets along c-axis direction due to the julolidine compound selective adsorbing on the positive (0 0 0 1) facets by coordinating Zn cations with its N atoms. Systematic reactions in the presence of different amounts of DMF were conducted to control the formation of various well-shaped ZnO crystals. The selective adsorption of julolidine on the growing facets resulted in the formation of grooved hexagonal disks, hexagonal disks, hexagonal pyramids, and hexagonal rods.
AB - Micro-sized ZnO crystals with different shapes have been successfully synthesized by a simple solvothermal reaction of zinc nitrate hexahydrate and julolidine in N, N-dimethylformamide (DMF). The growth of ZnO crystals with tunable shape was controlled through a suppressed crystal growth of the (0 0 0 1) facets along c-axis direction due to the julolidine compound selective adsorbing on the positive (0 0 0 1) facets by coordinating Zn cations with its N atoms. Systematic reactions in the presence of different amounts of DMF were conducted to control the formation of various well-shaped ZnO crystals. The selective adsorption of julolidine on the growing facets resulted in the formation of grooved hexagonal disks, hexagonal disks, hexagonal pyramids, and hexagonal rods.
KW - A1. Crystal morphology
KW - A1. Crystal structure
KW - A2. Growth from solutions
KW - A2. Single crystal growth
KW - B1. Inorganic compounds
UR - http://www.scopus.com/inward/record.url?scp=77249168226&partnerID=8YFLogxK
U2 - 10.1016/j.jcrysgro.2010.01.008
DO - 10.1016/j.jcrysgro.2010.01.008
M3 - Article
AN - SCOPUS:77249168226
VL - 312
SP - 947
EP - 952
JO - Journal of crystal growth
JF - Journal of crystal growth
SN - 0022-0248
IS - 7
ER -