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| Titel in Übersetzung | Aufbau von Kohlenstoffgerüsten mit Hilfe von Rutheniumkomplexen: 1,5-Cyclooctadien als Reagens in übergangsmetallkatalysierten Reaktionen |
|---|---|
| Originalsprache | Englisch |
| Seiten (von - bis) | 636-638 |
| Seitenumfang | 3 |
| Fachzeitschrift | Angewandte Chemie International Edition in English |
| Jahrgang | 33 |
| Ausgabenummer | 6 |
| Publikationsstatus | Veröffentlicht - 31 März 1994 |
Abstract
Hitherto 1,5‐cyclooctadiene (COD) was used almost exclusively as a ligand in transition metal complexes; however, Trost et al. have recently found a ruthenium‐catalyzed reaction, in which COD functions as bis‐homodiene and undergoes a cyclization with alkynes to form derivatives of the tricyclo‐[4.2.2.02, 5]dec‐7‐ene (1) in good yields. Thus, COD may now be considered as a synthetic building block. (Figure Presented.)
ASJC Scopus Sachgebiete
- Chemische Verfahrenstechnik (insg.)
- Katalyse
- Chemie (insg.)
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in: Angewandte Chemie International Edition in English, Jahrgang 33, Nr. 6, 31.03.1994, S. 636-638.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Construction of Carbon Frameworks with the Help of Ruthenium Complexes
T2 - 1,5‐Cyclooctadiene as a Reagent in Transition Metal Catalyzed Reactions
AU - Butenschön, Holger
PY - 1994/3/31
Y1 - 1994/3/31
N2 - Hitherto 1,5‐cyclooctadiene (COD) was used almost exclusively as a ligand in transition metal complexes; however, Trost et al. have recently found a ruthenium‐catalyzed reaction, in which COD functions as bis‐homodiene and undergoes a cyclization with alkynes to form derivatives of the tricyclo‐[4.2.2.02, 5]dec‐7‐ene (1) in good yields. Thus, COD may now be considered as a synthetic building block. (Figure Presented.)
AB - Hitherto 1,5‐cyclooctadiene (COD) was used almost exclusively as a ligand in transition metal complexes; however, Trost et al. have recently found a ruthenium‐catalyzed reaction, in which COD functions as bis‐homodiene and undergoes a cyclization with alkynes to form derivatives of the tricyclo‐[4.2.2.02, 5]dec‐7‐ene (1) in good yields. Thus, COD may now be considered as a synthetic building block. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=33748213812&partnerID=8YFLogxK
U2 - 10.1002/anie.199406361
DO - 10.1002/anie.199406361
M3 - Article
AN - SCOPUS:33748213812
VL - 33
SP - 636
EP - 638
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
SN - 0570-0833
IS - 6
ER -