Compatibility of hydrogen transfer via Pd-membranes with the rates of heterogeneously catalysed steam reforming

Publikation: Beitrag in Fachzeitschrift › Konferenzaufsatz in Fachzeitschrift › Forschung › Peer-Review

Autoren

  • Alexandra Kleinert
  • Gerd Grubert
  • Xiulian Pan
  • Christof Hamel
  • Andreas Seidel-Morgenstern
  • Jürgen Caro

Organisationseinheiten

Externe Organisationen

  • Fraunhofer-Institut für Grenzflächen- und Bioverfahrenstechnik (IGB)
  • Max-Planck-Institut für Dynamik komplexer technischer Systeme
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)267-273
Seitenumfang7
FachzeitschriftCatalysis today
Jahrgang104
Ausgabenummer2-4
PublikationsstatusElektronisch veröffentlicht (E-Pub) - 10 Mai 2005
Veranstaltung6th International Conference on Catalysis in Membrane Reactors 2004 - Lahnstein, Deutschland
Dauer: 6 Juli 2004 → 9 Juli 2004

Abstract

For an effective operation of a membrane reactor in comparison with a conventional fixed-bed reactor, the kinetic compatibility of hydrogen production and its removal is essential. The aim of this work is to provide an estimation of the membrane area needed for the extraction of the hydrogen which is produced at a defined gas hourly space velocity (GHSV) in steam reforming of methane (SR). The SR was studied in a fixed-bed reactor using a conventional Ni-catalyst for evaluating the kinetic parameters. The conversion of methane was simulated by a one-dimensional, non-isothermal reactor model and compared with the experimental results. Hydrogen conducting Pd-membranes were prepared by electroless plating, and the hydrogen permeation through these membranes was determined. The analysis performed can provide an estimation for the design of a catalytic membrane reactor.

ASJC Scopus Sachgebiete

Ziele für nachhaltige Entwicklung

Zitieren

Compatibility of hydrogen transfer via Pd-membranes with the rates of heterogeneously catalysed steam reforming. / Kleinert, Alexandra; Grubert, Gerd; Pan, Xiulian et al.
in: Catalysis today, Jahrgang 104, Nr. 2-4, 10.05.2005, S. 267-273.

Publikation: Beitrag in Fachzeitschrift › Konferenzaufsatz in Fachzeitschrift › Forschung › Peer-Review

Kleinert, A, Grubert, G, Pan, X, Hamel, C, Seidel-Morgenstern, A & Caro, J 2005, 'Compatibility of hydrogen transfer via Pd-membranes with the rates of heterogeneously catalysed steam reforming', Catalysis today, Jg. 104, Nr. 2-4, S. 267-273. https://doi.org/10.1016/j.cattod.2005.03.068
Kleinert, A., Grubert, G., Pan, X., Hamel, C., Seidel-Morgenstern, A., & Caro, J. (2005). Compatibility of hydrogen transfer via Pd-membranes with the rates of heterogeneously catalysed steam reforming. Catalysis today, 104(2-4), 267-273. Vorabveröffentlichung online. https://doi.org/10.1016/j.cattod.2005.03.068
Kleinert A, Grubert G, Pan X, Hamel C, Seidel-Morgenstern A, Caro J. Compatibility of hydrogen transfer via Pd-membranes with the rates of heterogeneously catalysed steam reforming. Catalysis today. 2005 Mai 10;104(2-4):267-273. Epub 2005 Mai 10. doi: 10.1016/j.cattod.2005.03.068
Kleinert, Alexandra ; Grubert, Gerd ; Pan, Xiulian et al. / Compatibility of hydrogen transfer via Pd-membranes with the rates of heterogeneously catalysed steam reforming. in: Catalysis today. 2005 ; Jahrgang 104, Nr. 2-4. S. 267-273.
Download
@article{7cb7c31f89dc40e78271d3d8904e1d2c,
title = "Compatibility of hydrogen transfer via Pd-membranes with the rates of heterogeneously catalysed steam reforming",
abstract = "For an effective operation of a membrane reactor in comparison with a conventional fixed-bed reactor, the kinetic compatibility of hydrogen production and its removal is essential. The aim of this work is to provide an estimation of the membrane area needed for the extraction of the hydrogen which is produced at a defined gas hourly space velocity (GHSV) in steam reforming of methane (SR). The SR was studied in a fixed-bed reactor using a conventional Ni-catalyst for evaluating the kinetic parameters. The conversion of methane was simulated by a one-dimensional, non-isothermal reactor model and compared with the experimental results. Hydrogen conducting Pd-membranes were prepared by electroless plating, and the hydrogen permeation through these membranes was determined. The analysis performed can provide an estimation for the design of a catalytic membrane reactor.",
keywords = "Gas hourly space velocity, Pd-membranes, Steam reforming",
author = "Alexandra Kleinert and Gerd Grubert and Xiulian Pan and Christof Hamel and Andreas Seidel-Morgenstern and J{\"u}rgen Caro",
year = "2005",
month = may,
day = "10",
doi = "10.1016/j.cattod.2005.03.068",
language = "English",
volume = "104",
pages = "267--273",
journal = "Catalysis today",
issn = "0920-5861",
publisher = "Elsevier",
number = "2-4",
note = "6th International Conference on Catalysis in Membrane Reactors 2004 ; Conference date: 06-07-2004 Through 09-07-2004",

}

Download

TY - JOUR

T1 - Compatibility of hydrogen transfer via Pd-membranes with the rates of heterogeneously catalysed steam reforming

AU - Kleinert, Alexandra

AU - Grubert, Gerd

AU - Pan, Xiulian

AU - Hamel, Christof

AU - Seidel-Morgenstern, Andreas

AU - Caro, Jürgen

PY - 2005/5/10

Y1 - 2005/5/10

N2 - For an effective operation of a membrane reactor in comparison with a conventional fixed-bed reactor, the kinetic compatibility of hydrogen production and its removal is essential. The aim of this work is to provide an estimation of the membrane area needed for the extraction of the hydrogen which is produced at a defined gas hourly space velocity (GHSV) in steam reforming of methane (SR). The SR was studied in a fixed-bed reactor using a conventional Ni-catalyst for evaluating the kinetic parameters. The conversion of methane was simulated by a one-dimensional, non-isothermal reactor model and compared with the experimental results. Hydrogen conducting Pd-membranes were prepared by electroless plating, and the hydrogen permeation through these membranes was determined. The analysis performed can provide an estimation for the design of a catalytic membrane reactor.

AB - For an effective operation of a membrane reactor in comparison with a conventional fixed-bed reactor, the kinetic compatibility of hydrogen production and its removal is essential. The aim of this work is to provide an estimation of the membrane area needed for the extraction of the hydrogen which is produced at a defined gas hourly space velocity (GHSV) in steam reforming of methane (SR). The SR was studied in a fixed-bed reactor using a conventional Ni-catalyst for evaluating the kinetic parameters. The conversion of methane was simulated by a one-dimensional, non-isothermal reactor model and compared with the experimental results. Hydrogen conducting Pd-membranes were prepared by electroless plating, and the hydrogen permeation through these membranes was determined. The analysis performed can provide an estimation for the design of a catalytic membrane reactor.

KW - Gas hourly space velocity

KW - Pd-membranes

KW - Steam reforming

UR - http://www.scopus.com/inward/record.url?scp=31344449957&partnerID=8YFLogxK

U2 - 10.1016/j.cattod.2005.03.068

DO - 10.1016/j.cattod.2005.03.068

M3 - Conference article

AN - SCOPUS:31344449957

VL - 104

SP - 267

EP - 273

JO - Catalysis today

JF - Catalysis today

SN - 0920-5861

IS - 2-4

T2 - 6th International Conference on Catalysis in Membrane Reactors 2004

Y2 - 6 July 2004 through 9 July 2004

ER -