Details
| Originalsprache | Englisch |
|---|---|
| Aufsatznummer | GB3016 |
| Fachzeitschrift | Global biogeochemical cycles |
| Jahrgang | 21 |
| Ausgabenummer | 3 |
| Publikationsstatus | Veröffentlicht - 31 Aug. 2007 |
| Extern publiziert | Ja |
Abstract
Black carbon (BC), the product of incomplete combustion of fossil fuels and biomass (called elemental carbon (EC) in atmospheric sciences), was quantified in 12 different materials by 17 laboratories from different disciplines, using seven different methods. The materials were divided into three classes: (1) potentially interfering materials, (2) laboratory-produced BC-rich materials, and (3) BC-containing environmental matrices (from soil, water, sediment, and atmosphere). This is the first comprehensive intercomparison of this type (multimethod, multilab, and multisample), focusing mainly on methods used for soil and sediment BC studies. Results for the potentially interfering materials (which by definition contained no fire-derived organic carbon) highlighted situations where individual methods may overestimate BC concentrations. Results for the BC-rich materials (one soot and two chars) showed that some of the methods identified most of the carbon in all three materials as BC, whereas other methods identified only soot carbon as BC. The different methods also gave widely different BC contents for the environmental matrices. However, these variations could be understood in the light of the findings for the other two groups of materials, i.e., that some methods incorrectly identify non-BC carbon as BC, and that the detection efficiency of each technique varies across the BC continuum. We found that atmospheric BC quantification methods are not ideal for soil and sediment studies as in their methodology these incorporate the definition of BC as light-absorbing material irrespective of its origin, leading to biases when applied to terrestrial and sedimentary materials. This study shows that any attempt to merge data generated via different methods must consider the different, operationally defined analytical windows of the BC continuum detected by each technique, as well as the limitations and potential biases of each technique. A major goal of this ring trial was to provide a basis on which to choose between the different BC quantification methods in soil and sediment studies. In this paper we summarize the advantages and disadvantages of each method. In future studies, we strongly recommend the evaluation of all methods analyzing for BC in soils and sediments against the set of BC reference materials analyzed here.
ASJC Scopus Sachgebiete
- Umweltwissenschaften (insg.)
- Globaler Wandel
- Umweltwissenschaften (insg.)
- Umweltchemie
- Umweltwissenschaften (insg.)
- Allgemeine Umweltwissenschaft
- Erdkunde und Planetologie (insg.)
- Atmosphärenwissenschaften
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in: Global biogeochemical cycles, Jahrgang 21, Nr. 3, GB3016, 31.08.2007.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Comparison of quantification methods to measure fire-derived (black/elemental) carbon in soils and sediments using reference materials from soil, water, sediment and the atmosphere
AU - Hammes, Karen
AU - Schmidt, Michael W.I.
AU - Smernik, Ronald J.
AU - Currie, Lloyd A.
AU - Ball, William P.
AU - Nguyen, Thanh H.
AU - Louchouarn, Patrick
AU - Houel, Stephane
AU - Gustafsson, Örjan
AU - Elmquist, Marie
AU - Cornelissen, Gerard
AU - Skjemstad, Jan O.
AU - Masiello, Caroline A.
AU - Song, Jianzhong
AU - Peng, Ping'an
AU - Mitra, Siddhartha
AU - Dunn, Joshua C.
AU - Hatcher, Patrick G.
AU - Hockaday, William C.
AU - Smith, Dwight M.
AU - Hartkopf-Fröder, Christoph
AU - Böhmer, Axel
AU - Lüer, Burkhard
AU - Huebert, Barry J.
AU - Amelung, Wulf
AU - Brodowski, Sonja
AU - Huang, Lin
AU - Zhang, Wendy
AU - Gschwend, Philip M.
AU - Flores-Cervantes, D. Xanat
AU - Largeau, Claude
AU - Rouzaud, Jean Noël
AU - Rumpel, Cornelia
AU - Guggenberger, Georg
AU - Kaiser, Klaus
AU - Rodionov, Andrei
AU - Gonzalez-Vila, Francisco J.
AU - Gonzalez-Perez, José S.
AU - de la Rosa, José M.
AU - Manning, David A.C.
AU - López-Capél, Elisa
AU - Ding, Luyi
PY - 2007/8/31
Y1 - 2007/8/31
N2 - Black carbon (BC), the product of incomplete combustion of fossil fuels and biomass (called elemental carbon (EC) in atmospheric sciences), was quantified in 12 different materials by 17 laboratories from different disciplines, using seven different methods. The materials were divided into three classes: (1) potentially interfering materials, (2) laboratory-produced BC-rich materials, and (3) BC-containing environmental matrices (from soil, water, sediment, and atmosphere). This is the first comprehensive intercomparison of this type (multimethod, multilab, and multisample), focusing mainly on methods used for soil and sediment BC studies. Results for the potentially interfering materials (which by definition contained no fire-derived organic carbon) highlighted situations where individual methods may overestimate BC concentrations. Results for the BC-rich materials (one soot and two chars) showed that some of the methods identified most of the carbon in all three materials as BC, whereas other methods identified only soot carbon as BC. The different methods also gave widely different BC contents for the environmental matrices. However, these variations could be understood in the light of the findings for the other two groups of materials, i.e., that some methods incorrectly identify non-BC carbon as BC, and that the detection efficiency of each technique varies across the BC continuum. We found that atmospheric BC quantification methods are not ideal for soil and sediment studies as in their methodology these incorporate the definition of BC as light-absorbing material irrespective of its origin, leading to biases when applied to terrestrial and sedimentary materials. This study shows that any attempt to merge data generated via different methods must consider the different, operationally defined analytical windows of the BC continuum detected by each technique, as well as the limitations and potential biases of each technique. A major goal of this ring trial was to provide a basis on which to choose between the different BC quantification methods in soil and sediment studies. In this paper we summarize the advantages and disadvantages of each method. In future studies, we strongly recommend the evaluation of all methods analyzing for BC in soils and sediments against the set of BC reference materials analyzed here.
AB - Black carbon (BC), the product of incomplete combustion of fossil fuels and biomass (called elemental carbon (EC) in atmospheric sciences), was quantified in 12 different materials by 17 laboratories from different disciplines, using seven different methods. The materials were divided into three classes: (1) potentially interfering materials, (2) laboratory-produced BC-rich materials, and (3) BC-containing environmental matrices (from soil, water, sediment, and atmosphere). This is the first comprehensive intercomparison of this type (multimethod, multilab, and multisample), focusing mainly on methods used for soil and sediment BC studies. Results for the potentially interfering materials (which by definition contained no fire-derived organic carbon) highlighted situations where individual methods may overestimate BC concentrations. Results for the BC-rich materials (one soot and two chars) showed that some of the methods identified most of the carbon in all three materials as BC, whereas other methods identified only soot carbon as BC. The different methods also gave widely different BC contents for the environmental matrices. However, these variations could be understood in the light of the findings for the other two groups of materials, i.e., that some methods incorrectly identify non-BC carbon as BC, and that the detection efficiency of each technique varies across the BC continuum. We found that atmospheric BC quantification methods are not ideal for soil and sediment studies as in their methodology these incorporate the definition of BC as light-absorbing material irrespective of its origin, leading to biases when applied to terrestrial and sedimentary materials. This study shows that any attempt to merge data generated via different methods must consider the different, operationally defined analytical windows of the BC continuum detected by each technique, as well as the limitations and potential biases of each technique. A major goal of this ring trial was to provide a basis on which to choose between the different BC quantification methods in soil and sediment studies. In this paper we summarize the advantages and disadvantages of each method. In future studies, we strongly recommend the evaluation of all methods analyzing for BC in soils and sediments against the set of BC reference materials analyzed here.
UR - http://www.scopus.com/inward/record.url?scp=36749022108&partnerID=8YFLogxK
U2 - 10.1029/2006GB002914
DO - 10.1029/2006GB002914
M3 - Article
AN - SCOPUS:36749022108
VL - 21
JO - Global biogeochemical cycles
JF - Global biogeochemical cycles
SN - 0886-6236
IS - 3
M1 - GB3016
ER -