Codoping Strategy to Improve Stability and Permeability of Ba0.6Sr0.4FeO3-δ-Based Perovskite Membranes

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Autoren

  • Guanghu He
  • Zhengwen Cao
  • Wenyuan Liang
  • Yan Zhang
  • Xin Liu
  • Jürgen Caro
  • Heqing Jiang

Organisationseinheiten

Externe Organisationen

  • Qingdao Institute Of Bioenergy & Bioprocess Technology Chinese Academy Of Sciences
  • Max-Planck-Institut für Kohlenforschung
  • CAS - Dalian Institute of Chemical Physics
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)10386-10393
Seitenumfang8
FachzeitschriftIndustrial and Engineering Chemistry Research
Jahrgang55
Ausgabenummer39
Frühes Online-Datum23 Sept. 2016
PublikationsstatusElektronisch veröffentlicht (E-Pub) - 23 Sept. 2016

Abstract

To improve the stability and oxygen permeability of Ba0.6Sr0.4FeO3-δ (BSF)-based perovskite membranes, an Mg and Zr codoping strategy is proposed. The characterization by X-ray diffraction, Mössbauer spectroscopy and oxygen permeation measurements revealed that single-element Mg doping could improve the oxygen permeability of BSF-based membranes. However, in situ XRD measurements indicated that the single-element Mg doping exhibits a poor thermal stability at low oxygen partial pressure. Single-element Zr doping could improve the structure stability of BSF-based perovskites but lead to a serious decrease of oxygen permeability. Compared with the BSF-based perovskites doped by either Mg or Zr alone, Mg and Zr codoped perovskite Ba0.6Sr0.4Fe0.8Mg0.15Zr0.05O3-δ showed a better stability than single-element Mg doping and exhibited a higher oxygen permeability than single-element Zr doping. For the Mg and Zr codoped BSF, the oxygen permeation flux reached 0.78 mL min-1 cm-2 at 950 °C under an air/He oxygen partial pressure gradient.

ASJC Scopus Sachgebiete

Zitieren

Codoping Strategy to Improve Stability and Permeability of Ba0.6Sr0.4FeO3-δ-Based Perovskite Membranes. / He, Guanghu; Cao, Zhengwen; Liang, Wenyuan et al.
in: Industrial and Engineering Chemistry Research, Jahrgang 55, Nr. 39, 23.09.2016, S. 10386-10393.

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

He, G., Cao, Z., Liang, W., Zhang, Y., Liu, X., Caro, J., & Jiang, H. (2016). Codoping Strategy to Improve Stability and Permeability of Ba0.6Sr0.4FeO3-δ-Based Perovskite Membranes. Industrial and Engineering Chemistry Research, 55(39), 10386-10393. Vorabveröffentlichung online. https://doi.org/10.1021/acs.iecr.6b02134
He G, Cao Z, Liang W, Zhang Y, Liu X, Caro J et al. Codoping Strategy to Improve Stability and Permeability of Ba0.6Sr0.4FeO3-δ-Based Perovskite Membranes. Industrial and Engineering Chemistry Research. 2016 Sep 23;55(39):10386-10393. Epub 2016 Sep 23. doi: 10.1021/acs.iecr.6b02134
He, Guanghu ; Cao, Zhengwen ; Liang, Wenyuan et al. / Codoping Strategy to Improve Stability and Permeability of Ba0.6Sr0.4FeO3-δ-Based Perovskite Membranes. in: Industrial and Engineering Chemistry Research. 2016 ; Jahrgang 55, Nr. 39. S. 10386-10393.
Download
@article{8e7aecefff824f66b2a7015fb78dead7,
title = "Codoping Strategy to Improve Stability and Permeability of Ba0.6Sr0.4FeO3-δ-Based Perovskite Membranes",
abstract = "To improve the stability and oxygen permeability of Ba0.6Sr0.4FeO3-δ (BSF)-based perovskite membranes, an Mg and Zr codoping strategy is proposed. The characterization by X-ray diffraction, M{\"o}ssbauer spectroscopy and oxygen permeation measurements revealed that single-element Mg doping could improve the oxygen permeability of BSF-based membranes. However, in situ XRD measurements indicated that the single-element Mg doping exhibits a poor thermal stability at low oxygen partial pressure. Single-element Zr doping could improve the structure stability of BSF-based perovskites but lead to a serious decrease of oxygen permeability. Compared with the BSF-based perovskites doped by either Mg or Zr alone, Mg and Zr codoped perovskite Ba0.6Sr0.4Fe0.8Mg0.15Zr0.05O3-δ showed a better stability than single-element Mg doping and exhibited a higher oxygen permeability than single-element Zr doping. For the Mg and Zr codoped BSF, the oxygen permeation flux reached 0.78 mL min-1 cm-2 at 950 °C under an air/He oxygen partial pressure gradient.",
author = "Guanghu He and Zhengwen Cao and Wenyuan Liang and Yan Zhang and Xin Liu and J{\"u}rgen Caro and Heqing Jiang",
year = "2016",
month = sep,
day = "23",
doi = "10.1021/acs.iecr.6b02134",
language = "English",
volume = "55",
pages = "10386--10393",
journal = "Industrial and Engineering Chemistry Research",
issn = "0888-5885",
publisher = "American Chemical Society",
number = "39",

}

Download

TY - JOUR

T1 - Codoping Strategy to Improve Stability and Permeability of Ba0.6Sr0.4FeO3-δ-Based Perovskite Membranes

AU - He, Guanghu

AU - Cao, Zhengwen

AU - Liang, Wenyuan

AU - Zhang, Yan

AU - Liu, Xin

AU - Caro, Jürgen

AU - Jiang, Heqing

PY - 2016/9/23

Y1 - 2016/9/23

N2 - To improve the stability and oxygen permeability of Ba0.6Sr0.4FeO3-δ (BSF)-based perovskite membranes, an Mg and Zr codoping strategy is proposed. The characterization by X-ray diffraction, Mössbauer spectroscopy and oxygen permeation measurements revealed that single-element Mg doping could improve the oxygen permeability of BSF-based membranes. However, in situ XRD measurements indicated that the single-element Mg doping exhibits a poor thermal stability at low oxygen partial pressure. Single-element Zr doping could improve the structure stability of BSF-based perovskites but lead to a serious decrease of oxygen permeability. Compared with the BSF-based perovskites doped by either Mg or Zr alone, Mg and Zr codoped perovskite Ba0.6Sr0.4Fe0.8Mg0.15Zr0.05O3-δ showed a better stability than single-element Mg doping and exhibited a higher oxygen permeability than single-element Zr doping. For the Mg and Zr codoped BSF, the oxygen permeation flux reached 0.78 mL min-1 cm-2 at 950 °C under an air/He oxygen partial pressure gradient.

AB - To improve the stability and oxygen permeability of Ba0.6Sr0.4FeO3-δ (BSF)-based perovskite membranes, an Mg and Zr codoping strategy is proposed. The characterization by X-ray diffraction, Mössbauer spectroscopy and oxygen permeation measurements revealed that single-element Mg doping could improve the oxygen permeability of BSF-based membranes. However, in situ XRD measurements indicated that the single-element Mg doping exhibits a poor thermal stability at low oxygen partial pressure. Single-element Zr doping could improve the structure stability of BSF-based perovskites but lead to a serious decrease of oxygen permeability. Compared with the BSF-based perovskites doped by either Mg or Zr alone, Mg and Zr codoped perovskite Ba0.6Sr0.4Fe0.8Mg0.15Zr0.05O3-δ showed a better stability than single-element Mg doping and exhibited a higher oxygen permeability than single-element Zr doping. For the Mg and Zr codoped BSF, the oxygen permeation flux reached 0.78 mL min-1 cm-2 at 950 °C under an air/He oxygen partial pressure gradient.

UR - http://www.scopus.com/inward/record.url?scp=84989878244&partnerID=8YFLogxK

U2 - 10.1021/acs.iecr.6b02134

DO - 10.1021/acs.iecr.6b02134

M3 - Article

AN - SCOPUS:84989878244

VL - 55

SP - 10386

EP - 10393

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

SN - 0888-5885

IS - 39

ER -