Charged fluorophores-assisted fabrication of metallic structures inside hydrogel by multi-photon photoreduction

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

Autoren

  • Manan MacHida
  • Weilu Shen
  • Hiroaki Onoe
  • Alexander Heisterkamp
  • Eric Mazur
  • Mitsuhiro Terakawa

Organisationseinheiten

Externe Organisationen

  • Keio University
  • Harvard University
  • Laser Zentrum Hannover e.V. (LZH)
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Titel des SammelwerksFrontiers in Ultrafast Optics
UntertitelBiomedical, Scientific, and Industrial Applications XXI
Herausgeber/-innenPeter R. Herman, Michel Meunier, Roberto Osellame
Herausgeber (Verlag)SPIE
ISBN (elektronisch)9781510641877
PublikationsstatusVeröffentlicht - 5 März 2021
VeranstaltungFrontiers in Ultrafast Optics: Biomedical, Scientific, and Industrial Applications XXI 2021 - Virtual, Online, USA / Vereinigte Staaten
Dauer: 6 März 202111 März 2021

Publikationsreihe

NameProceedings of SPIE - The International Society for Optical Engineering
Band11676
ISSN (Print)0277-786X
ISSN (elektronisch)1996-756X

Abstract

We demonstrated the fabrication of gold microstructures inside a PEG-based hydrogel with different charged fluorophores by multi-photon photoreduction. By adding an anionic charged FITC-dextran or a cationic charged Rhodamine110 to the metal ion solution, line width of the fabricated gold microstructures increased compared to that of the structures fabricated in fluorophore-free hydrogel. The photobleaching could enhanced the reduction of gold ions accompanying the oxidation of the fluorophores. Notably, the inhibition of reduction of gold ions at a site other than the focal point was observed with FITC-dextran, which may be attributable to the coordination of gold ions to FITC-dextran.

ASJC Scopus Sachgebiete

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Charged fluorophores-assisted fabrication of metallic structures inside hydrogel by multi-photon photoreduction. / MacHida, Manan; Shen, Weilu; Onoe, Hiroaki et al.
Frontiers in Ultrafast Optics: Biomedical, Scientific, and Industrial Applications XXI. Hrsg. / Peter R. Herman; Michel Meunier; Roberto Osellame. SPIE, 2021. 116760R (Proceedings of SPIE - The International Society for Optical Engineering; Band 11676).

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

MacHida, M, Shen, W, Onoe, H, Heisterkamp, A, Mazur, E & Terakawa, M 2021, Charged fluorophores-assisted fabrication of metallic structures inside hydrogel by multi-photon photoreduction. in PR Herman, M Meunier & R Osellame (Hrsg.), Frontiers in Ultrafast Optics: Biomedical, Scientific, and Industrial Applications XXI., 116760R, Proceedings of SPIE - The International Society for Optical Engineering, Bd. 11676, SPIE, Frontiers in Ultrafast Optics: Biomedical, Scientific, and Industrial Applications XXI 2021, Virtual, Online, USA / Vereinigte Staaten, 6 März 2021. https://doi.org/10.1117/12.2578247
MacHida, M., Shen, W., Onoe, H., Heisterkamp, A., Mazur, E., & Terakawa, M. (2021). Charged fluorophores-assisted fabrication of metallic structures inside hydrogel by multi-photon photoreduction. In P. R. Herman, M. Meunier, & R. Osellame (Hrsg.), Frontiers in Ultrafast Optics: Biomedical, Scientific, and Industrial Applications XXI Artikel 116760R (Proceedings of SPIE - The International Society for Optical Engineering; Band 11676). SPIE. https://doi.org/10.1117/12.2578247
MacHida M, Shen W, Onoe H, Heisterkamp A, Mazur E, Terakawa M. Charged fluorophores-assisted fabrication of metallic structures inside hydrogel by multi-photon photoreduction. in Herman PR, Meunier M, Osellame R, Hrsg., Frontiers in Ultrafast Optics: Biomedical, Scientific, and Industrial Applications XXI. SPIE. 2021. 116760R. (Proceedings of SPIE - The International Society for Optical Engineering). doi: 10.1117/12.2578247
MacHida, Manan ; Shen, Weilu ; Onoe, Hiroaki et al. / Charged fluorophores-assisted fabrication of metallic structures inside hydrogel by multi-photon photoreduction. Frontiers in Ultrafast Optics: Biomedical, Scientific, and Industrial Applications XXI. Hrsg. / Peter R. Herman ; Michel Meunier ; Roberto Osellame. SPIE, 2021. (Proceedings of SPIE - The International Society for Optical Engineering).
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title = "Charged fluorophores-assisted fabrication of metallic structures inside hydrogel by multi-photon photoreduction",
abstract = "We demonstrated the fabrication of gold microstructures inside a PEG-based hydrogel with different charged fluorophores by multi-photon photoreduction. By adding an anionic charged FITC-dextran or a cationic charged Rhodamine110 to the metal ion solution, line width of the fabricated gold microstructures increased compared to that of the structures fabricated in fluorophore-free hydrogel. The photobleaching could enhanced the reduction of gold ions accompanying the oxidation of the fluorophores. Notably, the inhibition of reduction of gold ions at a site other than the focal point was observed with FITC-dextran, which may be attributable to the coordination of gold ions to FITC-dextran.",
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note = "Funding Information: This study was supported in part by a grant from Ministry of Education, Culture, Sports, Science and Technology (MEXT) KAKENHI (JP18H03551) and Japan Society for the Promotion of Science Grant-in-Aid for JSPS Fellows (JP20J13150).; Frontiers in Ultrafast Optics: Biomedical, Scientific, and Industrial Applications XXI 2021 ; Conference date: 06-03-2021 Through 11-03-2021",
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Download

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T1 - Charged fluorophores-assisted fabrication of metallic structures inside hydrogel by multi-photon photoreduction

AU - MacHida, Manan

AU - Shen, Weilu

AU - Onoe, Hiroaki

AU - Heisterkamp, Alexander

AU - Mazur, Eric

AU - Terakawa, Mitsuhiro

N1 - Funding Information: This study was supported in part by a grant from Ministry of Education, Culture, Sports, Science and Technology (MEXT) KAKENHI (JP18H03551) and Japan Society for the Promotion of Science Grant-in-Aid for JSPS Fellows (JP20J13150).

PY - 2021/3/5

Y1 - 2021/3/5

N2 - We demonstrated the fabrication of gold microstructures inside a PEG-based hydrogel with different charged fluorophores by multi-photon photoreduction. By adding an anionic charged FITC-dextran or a cationic charged Rhodamine110 to the metal ion solution, line width of the fabricated gold microstructures increased compared to that of the structures fabricated in fluorophore-free hydrogel. The photobleaching could enhanced the reduction of gold ions accompanying the oxidation of the fluorophores. Notably, the inhibition of reduction of gold ions at a site other than the focal point was observed with FITC-dextran, which may be attributable to the coordination of gold ions to FITC-dextran.

AB - We demonstrated the fabrication of gold microstructures inside a PEG-based hydrogel with different charged fluorophores by multi-photon photoreduction. By adding an anionic charged FITC-dextran or a cationic charged Rhodamine110 to the metal ion solution, line width of the fabricated gold microstructures increased compared to that of the structures fabricated in fluorophore-free hydrogel. The photobleaching could enhanced the reduction of gold ions accompanying the oxidation of the fluorophores. Notably, the inhibition of reduction of gold ions at a site other than the focal point was observed with FITC-dextran, which may be attributable to the coordination of gold ions to FITC-dextran.

KW - Femtosecond laser

KW - Fluorophore

KW - Gold

KW - Hydrogel

KW - Microfabrication

KW - Photoreduction

KW - Soft material

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AN - SCOPUS:85107184669

T3 - Proceedings of SPIE - The International Society for Optical Engineering

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PB - SPIE

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