Characterization of clay and fine silt fractions of forest soils by standardized K/Ca sorption isotherms

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Stefan Dultz
  • Nestor Pesci
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Details

OriginalspracheEnglisch
Seiten (von - bis)83-89
Seitenumfang7
FachzeitschriftJournal of Plant Nutrition and Soil Science
Jahrgang163
Ausgabenummer1
PublikationsstatusVeröffentlicht - 2000

Abstract

For better comparison of selectivity characteristics of clay and fine silt fractions sorption isotherms standardized on the cation exchange capacity (CEC) are useful. Due to the effect of the CEC on the sorption isotherms, it is necessary to characterize the exchanging substance with regard to different ion selectivities with standardized potassium/calcium-(K/Ca) sorption isotherms. This procedure helps to complete the knowledge about the mineralogical composition, which is obtained by X-ray powder diffractometry. A Haplic Luvisol from boulder marl shows distinct differences in its K selectivity both between different particle size fractions and different horizons. This is partly due to the presence of smectites and vermiculites which are differently distributed within the particle size fractions. The increase of K selectivity with increasing particle diameter in the calcareous C horizon can be attributed to the marginal expansion of mica/illite by Ca2+ ions. The K selectivity of individual particle size fractions in different horizons of a Gleyic Cambisol from glacial sand shows major similarities. If pedogenic chlorite is formed, no changes in selectivity characteristics can be observed.

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Characterization of clay and fine silt fractions of forest soils by standardized K/Ca sorption isotherms. / Dultz, Stefan; Pesci, Nestor.
in: Journal of Plant Nutrition and Soil Science, Jahrgang 163, Nr. 1, 2000, S. 83-89.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Dultz S, Pesci N. Characterization of clay and fine silt fractions of forest soils by standardized K/Ca sorption isotherms. Journal of Plant Nutrition and Soil Science. 2000;163(1):83-89. doi: 10.1002/(SICI)1522-2624(200002)163:1<83::AID-JPLN83>3.0.CO;2-Q
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AU - Dultz, Stefan

AU - Pesci, Nestor

N1 - Copyright: Copyright 2017 Elsevier B.V., All rights reserved.

PY - 2000

Y1 - 2000

N2 - For better comparison of selectivity characteristics of clay and fine silt fractions sorption isotherms standardized on the cation exchange capacity (CEC) are useful. Due to the effect of the CEC on the sorption isotherms, it is necessary to characterize the exchanging substance with regard to different ion selectivities with standardized potassium/calcium-(K/Ca) sorption isotherms. This procedure helps to complete the knowledge about the mineralogical composition, which is obtained by X-ray powder diffractometry. A Haplic Luvisol from boulder marl shows distinct differences in its K selectivity both between different particle size fractions and different horizons. This is partly due to the presence of smectites and vermiculites which are differently distributed within the particle size fractions. The increase of K selectivity with increasing particle diameter in the calcareous C horizon can be attributed to the marginal expansion of mica/illite by Ca2+ ions. The K selectivity of individual particle size fractions in different horizons of a Gleyic Cambisol from glacial sand shows major similarities. If pedogenic chlorite is formed, no changes in selectivity characteristics can be observed.

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KW - Cation exchange

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