Carbon blacks for lead-acid batteries in micro-hybrid applications: Studied by transmission electron microscopy and Raman spectroscopy

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Ellen Ebner
  • Daniel Burow
  • Jana Panke
  • Alexander Börger
  • Armin Feldhoff
  • Paolina Atanassova
  • Jesus Valenciano
  • Michael Wark
  • Eckart Rühl

Externe Organisationen

  • Volkswagen AG
  • Freie Universität Berlin (FU Berlin)
  • Cabot Corporation
  • Exide Technologies SLU
  • Ruhr-Universität Bochum
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)554-560
Seitenumfang7
FachzeitschriftJournal of Power Sources
Jahrgang222
Frühes Online-Datum12 Sept. 2012
PublikationsstatusVeröffentlicht - 15 Jan. 2013

Abstract

Micro-hybrid vehicles with stopestart function and regenerative braking lead to higher requirements on flooded lead-acid batteries. A promising approach to improve the cycleability of flooded lead-acid batteries is the use of carbon additives in the negative active mass. In this study different carbons (carbon blacks and a lamp black) were studied by transmission electron microscopy and Raman spectroscopy. Furthermore, batteries containing carbon blacks and lamp black in the negative active material were cycled with 17.5% depth of discharge. Morphology, surface functionalisation, and the degree of order were correlated with the cycle life. In cycling tests, batteries with highly ordered carbon blacks increase the lifetime of the corresponding battery by up to a factor of two.

Zitieren

Carbon blacks for lead-acid batteries in micro-hybrid applications: Studied by transmission electron microscopy and Raman spectroscopy. / Ebner, Ellen; Burow, Daniel; Panke, Jana et al.
in: Journal of Power Sources, Jahrgang 222, 15.01.2013, S. 554-560.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Ebner E, Burow D, Panke J, Börger A, Feldhoff A, Atanassova P et al. Carbon blacks for lead-acid batteries in micro-hybrid applications: Studied by transmission electron microscopy and Raman spectroscopy. Journal of Power Sources. 2013 Jan 15;222:554-560. Epub 2012 Sep 12. doi: 10.1016/j.jpowsour.2012.08.089
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abstract = "Micro-hybrid vehicles with stopestart function and regenerative braking lead to higher requirements on flooded lead-acid batteries. A promising approach to improve the cycleability of flooded lead-acid batteries is the use of carbon additives in the negative active mass. In this study different carbons (carbon blacks and a lamp black) were studied by transmission electron microscopy and Raman spectroscopy. Furthermore, batteries containing carbon blacks and lamp black in the negative active material were cycled with 17.5% depth of discharge. Morphology, surface functionalisation, and the degree of order were correlated with the cycle life. In cycling tests, batteries with highly ordered carbon blacks increase the lifetime of the corresponding battery by up to a factor of two.",
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T2 - Studied by transmission electron microscopy and Raman spectroscopy

AU - Ebner, Ellen

AU - Burow, Daniel

AU - Panke, Jana

AU - Börger, Alexander

AU - Feldhoff, Armin

AU - Atanassova, Paolina

AU - Valenciano, Jesus

AU - Wark, Michael

AU - Rühl, Eckart

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AB - Micro-hybrid vehicles with stopestart function and regenerative braking lead to higher requirements on flooded lead-acid batteries. A promising approach to improve the cycleability of flooded lead-acid batteries is the use of carbon additives in the negative active mass. In this study different carbons (carbon blacks and a lamp black) were studied by transmission electron microscopy and Raman spectroscopy. Furthermore, batteries containing carbon blacks and lamp black in the negative active material were cycled with 17.5% depth of discharge. Morphology, surface functionalisation, and the degree of order were correlated with the cycle life. In cycling tests, batteries with highly ordered carbon blacks increase the lifetime of the corresponding battery by up to a factor of two.

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KW - Enhanced flooded lead-acid batteries

KW - Micro-hybrid vehicles

KW - Negative active masses

KW - Raman spectroscopy

KW - Transmission electron microscopy

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