Boron-oxygen related lifetime degradation in p-type and n-type silicon

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

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  • MEMC Electronic Materials
  • Institut für Solarenergieforschung GmbH (ISFH)
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OriginalspracheEnglisch
Titel des SammelwerksHigh Purity Silicon 12
Herausgeber (Verlag)Electrochemical Society, Inc.
Seiten123-136
Seitenumfang14
Auflage5
ISBN (Print)9781607683537
PublikationsstatusVeröffentlicht - 2013
Extern publiziertJa
Veranstaltung12th High Purity Silicon Symposium - 222nd ECS Meeting - Honolulu, HI, USA / Vereinigte Staaten
Dauer: 7 Okt. 201211 Okt. 2012

Publikationsreihe

NameECS Transactions
Nummer5
Band50
ISSN (Print)1938-5862
ISSN (elektronisch)1938-6737

Abstract

Minority carrier lifetime degradation induced by illumination was studied in n-type Czochralski silicon co-doped with phosphorus and boron. The recombination centre that emerges during the degradation was found to be identical to the fast-stage centre (FRC) which is known for p-Si where it is produced at a rate proportional to the squared hole concentration, p 2. In n-type material where holes are excess carriers of a relatively low concentration, the time scale of FRC generation in n-Si is increased by several orders of magnitude. The generation kinetics is non-linear as a result of the dependence of p on the concentration of FRC. This non-linearity is well reproduced by simulations. An analysis of the injection level dependence of the minority carrier lifetime shows that FRC exists in 3 charge states (- 1, 0, +1) possessing 2 energy levels. The recombination is controlled by both levels. FRC is identified as a BsO2 complex of a substitutional boron and an oxygen dimer. The nature of the major lifetime-degrading centre in n-Si is thus different from that in p-Si - where the dominant one (a slow-stage centre, SRC) was found to be BiO2 - a complex involving an interstitial boron.

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Boron-oxygen related lifetime degradation in p-type and n-type silicon. / Voronkov, V. V.; Falster, R.; Lim, B. et al.
High Purity Silicon 12. 5. Aufl. Electrochemical Society, Inc., 2013. S. 123-136 (ECS Transactions; Band 50, Nr. 5).

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

Voronkov, VV, Falster, R, Lim, B & Schmidt, J 2013, Boron-oxygen related lifetime degradation in p-type and n-type silicon. in High Purity Silicon 12. 5 Aufl., ECS Transactions, Nr. 5, Bd. 50, Electrochemical Society, Inc., S. 123-136, 12th High Purity Silicon Symposium - 222nd ECS Meeting, Honolulu, HI, USA / Vereinigte Staaten, 7 Okt. 2012. https://doi.org/10.1149/05005.0123ecst
Voronkov, V. V., Falster, R., Lim, B., & Schmidt, J. (2013). Boron-oxygen related lifetime degradation in p-type and n-type silicon. In High Purity Silicon 12 (5 Aufl., S. 123-136). (ECS Transactions; Band 50, Nr. 5). Electrochemical Society, Inc.. https://doi.org/10.1149/05005.0123ecst
Voronkov VV, Falster R, Lim B, Schmidt J. Boron-oxygen related lifetime degradation in p-type and n-type silicon. in High Purity Silicon 12. 5 Aufl. Electrochemical Society, Inc. 2013. S. 123-136. (ECS Transactions; 5). doi: 10.1149/05005.0123ecst
Voronkov, V. V. ; Falster, R. ; Lim, B. et al. / Boron-oxygen related lifetime degradation in p-type and n-type silicon. High Purity Silicon 12. 5. Aufl. Electrochemical Society, Inc., 2013. S. 123-136 (ECS Transactions; 5).
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AU - Schmidt, J.

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AB - Minority carrier lifetime degradation induced by illumination was studied in n-type Czochralski silicon co-doped with phosphorus and boron. The recombination centre that emerges during the degradation was found to be identical to the fast-stage centre (FRC) which is known for p-Si where it is produced at a rate proportional to the squared hole concentration, p 2. In n-type material where holes are excess carriers of a relatively low concentration, the time scale of FRC generation in n-Si is increased by several orders of magnitude. The generation kinetics is non-linear as a result of the dependence of p on the concentration of FRC. This non-linearity is well reproduced by simulations. An analysis of the injection level dependence of the minority carrier lifetime shows that FRC exists in 3 charge states (- 1, 0, +1) possessing 2 energy levels. The recombination is controlled by both levels. FRC is identified as a BsO2 complex of a substitutional boron and an oxygen dimer. The nature of the major lifetime-degrading centre in n-Si is thus different from that in p-Si - where the dominant one (a slow-stage centre, SRC) was found to be BiO2 - a complex involving an interstitial boron.

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