Details
| Originalsprache | Deutsch |
|---|---|
| Seiten (von - bis) | 713-724 |
| Seitenumfang | 12 |
| Fachzeitschrift | Chemische Berichte |
| Jahrgang | 126 |
| Ausgabenummer | 3 |
| Publikationsstatus | Veröffentlicht - März 1993 |
| Extern publiziert | Ja |
Abstract
Three isomeric bicyclo[3.2.0]heptadienes 1 – 3 are compared by semiempirical calculations. Experimental attempts directed to the synthesis of derivatives of 1 are described. The synthesis, properties and some reactions of (η51‐bicyclo[3.2.0]hepta‐1,3‐dienyl)(η41‐cycloocta‐1,5‐diene)cobalt(I) (22), including an X‐ray crystal structure determination of the reaction product with diphenylethyne, the tetraphenylcyclobutadiene complex 30, are presented.
Schlagwörter
- Alkyne trimerization, Bicyclo[3.2.0]hepta‐1,3‐dienyl complexes, Calculations, semiempirical, Cobalt complexes
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in: Chemische Berichte, Jahrgang 126, Nr. 3, 03.1993, S. 713-724.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - (Bicyclo[3.2.0]hepta‐1,3‐dienyl)cobalt(I) Complexes
AU - Angermund, Klaus P.
AU - Betz, Peter
AU - Butenschön, Holger
PY - 1993/3
Y1 - 1993/3
N2 - Three isomeric bicyclo[3.2.0]heptadienes 1 – 3 are compared by semiempirical calculations. Experimental attempts directed to the synthesis of derivatives of 1 are described. The synthesis, properties and some reactions of (η51‐bicyclo[3.2.0]hepta‐1,3‐dienyl)(η41‐cycloocta‐1,5‐diene)cobalt(I) (22), including an X‐ray crystal structure determination of the reaction product with diphenylethyne, the tetraphenylcyclobutadiene complex 30, are presented.
AB - Three isomeric bicyclo[3.2.0]heptadienes 1 – 3 are compared by semiempirical calculations. Experimental attempts directed to the synthesis of derivatives of 1 are described. The synthesis, properties and some reactions of (η51‐bicyclo[3.2.0]hepta‐1,3‐dienyl)(η41‐cycloocta‐1,5‐diene)cobalt(I) (22), including an X‐ray crystal structure determination of the reaction product with diphenylethyne, the tetraphenylcyclobutadiene complex 30, are presented.
KW - Alkyne trimerization
KW - Bicyclo[3.2.0]hepta‐1,3‐dienyl complexes
KW - Calculations, semiempirical
KW - Cobalt complexes
UR - http://www.scopus.com/inward/record.url?scp=0037882497&partnerID=8YFLogxK
U2 - 10.1002/cber.19931260323
DO - 10.1002/cber.19931260323
M3 - Artikel
AN - SCOPUS:0037882497
VL - 126
SP - 713
EP - 724
JO - Chemische Berichte
JF - Chemische Berichte
SN - 0009-2940
IS - 3
ER -