Anisotropic effect after stretching of the spin-crossover compound [Fe(II)(2,6-bis-(benzimidazol-2′-yl)pyridine)2] (ClO4)2 in polyvinylalcohol polymer matrix

Publikation: Beitrag in FachzeitschriftKonferenzaufsatz in FachzeitschriftForschungPeer-Review

Autoren

  • Franz Renz
  • Miki Hasegawa
  • Toshihiku Hoshi
  • Usama El-Ayaan
  • Wolfgang Linert
  • Yutaka Fukuda

Externe Organisationen

  • Johannes Gutenberg-Universität Mainz
  • Aoyama Gakuin University
  • Technische Universität Wien (TUW)
  • Ochanomizu University
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Details

OriginalspracheEnglisch
Seiten (von - bis)1243-1252
Seitenumfang10
FachzeitschriftMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Jahrgang335
PublikationsstatusVeröffentlicht - 1999
Extern publiziertJa
Veranstaltung1998 6th International Conference on Molecule Based Magnets (ICMM'98) - Seignosse, France
Dauer: 12 Sept. 199817 Sept. 1998

Abstract

[Fe(II)(2,6-bis-(benzimidazol-2′-yl)-pyridine)2 ](ClO4)2 diffused into a poly(vinyl)alcohol polymer matrix, exhibits an thermally induced spin-crossover. After stretching the matrix, the compound orients itself in the matrix. Polarized UV/VIS spectra measured parallel and perpendicular to the stretching direction allowed to calculate the distortion of the molecule in the matrix by means of semi-empirical PPP SCF-CI calculations.

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Anisotropic effect after stretching of the spin-crossover compound [Fe(II)(2,6-bis-(benzimidazol-2′-yl)pyridine)2] (ClO4)2 in polyvinylalcohol polymer matrix. / Renz, Franz; Hasegawa, Miki; Hoshi, Toshihiku et al.
in: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Jahrgang 335, 1999, S. 1243-1252.

Publikation: Beitrag in FachzeitschriftKonferenzaufsatz in FachzeitschriftForschungPeer-Review

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title = "Anisotropic effect after stretching of the spin-crossover compound [Fe(II)(2,6-bis-(benzimidazol-2′-yl)pyridine)2] (ClO4)2 in polyvinylalcohol polymer matrix",
abstract = "[Fe(II)(2,6-bis-(benzimidazol-2′-yl)-pyridine)2 ](ClO4)2 diffused into a poly(vinyl)alcohol polymer matrix, exhibits an thermally induced spin-crossover. After stretching the matrix, the compound orients itself in the matrix. Polarized UV/VIS spectra measured parallel and perpendicular to the stretching direction allowed to calculate the distortion of the molecule in the matrix by means of semi-empirical PPP SCF-CI calculations.",
author = "Franz Renz and Miki Hasegawa and Toshihiku Hoshi and Usama El-Ayaan and Wolfgang Linert and Yutaka Fukuda",
year = "1999",
language = "English",
volume = "335",
pages = "1243--1252",
journal = "Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals",
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publisher = "Taylor and Francis Ltd.",
note = "1998 6th International Conference on Molecule Based Magnets (ICMM'98) ; Conference date: 12-09-1998 Through 17-09-1998",

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TY - JOUR

T1 - Anisotropic effect after stretching of the spin-crossover compound [Fe(II)(2,6-bis-(benzimidazol-2′-yl)pyridine)2] (ClO4)2 in polyvinylalcohol polymer matrix

AU - Renz, Franz

AU - Hasegawa, Miki

AU - Hoshi, Toshihiku

AU - El-Ayaan, Usama

AU - Linert, Wolfgang

AU - Fukuda, Yutaka

PY - 1999

Y1 - 1999

N2 - [Fe(II)(2,6-bis-(benzimidazol-2′-yl)-pyridine)2 ](ClO4)2 diffused into a poly(vinyl)alcohol polymer matrix, exhibits an thermally induced spin-crossover. After stretching the matrix, the compound orients itself in the matrix. Polarized UV/VIS spectra measured parallel and perpendicular to the stretching direction allowed to calculate the distortion of the molecule in the matrix by means of semi-empirical PPP SCF-CI calculations.

AB - [Fe(II)(2,6-bis-(benzimidazol-2′-yl)-pyridine)2 ](ClO4)2 diffused into a poly(vinyl)alcohol polymer matrix, exhibits an thermally induced spin-crossover. After stretching the matrix, the compound orients itself in the matrix. Polarized UV/VIS spectra measured parallel and perpendicular to the stretching direction allowed to calculate the distortion of the molecule in the matrix by means of semi-empirical PPP SCF-CI calculations.

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M3 - Conference article

AN - SCOPUS:0033352699

VL - 335

SP - 1243

EP - 1252

JO - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

SN - 1058-725X

T2 - 1998 6th International Conference on Molecule Based Magnets (ICMM'98)

Y2 - 12 September 1998 through 17 September 1998

ER -