TY - JOUR

T1 - Amorphous, turbostratic and crystalline carbon membranes with hydrogen selectivity

AU - Wollbrink, A.

AU - Volgmann, K.

AU - Koch, J.

AU - Kanthasamy, K.

AU - Tegenkamp, C.

AU - Li, Y.

AU - Richter, H.

AU - Kämnitz, S.

AU - Steinbach, F.

AU - Feldhoff, Armin

AU - Caro, Jürgen

N1 - Funding Information: The authors thank the Deutsche Forschungsgemeinschaft (DFG, Ca 147/19-1 and FE 928/7-1 ) and the National Natural Science Foundation of China (NSFC, 21322603 ) for financing the project “Hydrogen production from bio-ethane and bio-ethanol in catalytic membrane reactors”. The project partner X. Zhu (Dalian) is thanked for stimulating discussions. Publisher Copyright: © 2016 Elsevier Ltd.

PY - 2016/9/1

Y1 - 2016/9/1

N2 - Hydrogen production by catalytic steam reforming of renewable hydrocarbons like bio-methane or bio-ethanol has become an attractive goal of sustainable chemistry. Side reactions as in ethanol steam reforming decrease the hydrogen selectivity. A low-temperature catalytic membrane reactor with a hydrogen-selective membrane is expected to solve this problem. Three different carbon membranes are investigated with respect to their performance to extract hydrogen selectively from the binary and ternary reaction mixtures (H2/CO2), (H2/CO2/H2O), and (H2/ethanol) as model systems for bio-ethanol steam reforming. The three carbon membranes under study are (i) an amorphous carbon layer prepared by physical vapour deposition (PVD) of carbon on an porous alumina support using a carbon fibre yarn, (ii) a turbostratic carbon layer obtained by pyrolysis of a supported organic polymer blend as precursor, and (iii) a crystalline carbon prepared by pressing of graphite flakes into a self-supporting disc. For the equimolar binary feed mixture (H2/CO2) all carbon membranes were found to be hydrogen selective. For the ternary feed mixture (41vol.-% H2/41vol.-% CO2/18vol.-% H2O), in the case of the amorphous and crystalline carbon membrane, the hydrogen selectivity remains also in the presence of steam. The turbostratic carbon membrane separates preferentially steam (H2O) from the ternary feed mixture (H2/CO2/H2O).

AB - Hydrogen production by catalytic steam reforming of renewable hydrocarbons like bio-methane or bio-ethanol has become an attractive goal of sustainable chemistry. Side reactions as in ethanol steam reforming decrease the hydrogen selectivity. A low-temperature catalytic membrane reactor with a hydrogen-selective membrane is expected to solve this problem. Three different carbon membranes are investigated with respect to their performance to extract hydrogen selectively from the binary and ternary reaction mixtures (H2/CO2), (H2/CO2/H2O), and (H2/ethanol) as model systems for bio-ethanol steam reforming. The three carbon membranes under study are (i) an amorphous carbon layer prepared by physical vapour deposition (PVD) of carbon on an porous alumina support using a carbon fibre yarn, (ii) a turbostratic carbon layer obtained by pyrolysis of a supported organic polymer blend as precursor, and (iii) a crystalline carbon prepared by pressing of graphite flakes into a self-supporting disc. For the equimolar binary feed mixture (H2/CO2) all carbon membranes were found to be hydrogen selective. For the ternary feed mixture (41vol.-% H2/41vol.-% CO2/18vol.-% H2O), in the case of the amorphous and crystalline carbon membrane, the hydrogen selectivity remains also in the presence of steam. The turbostratic carbon membrane separates preferentially steam (H2O) from the ternary feed mixture (H2/CO2/H2O).

UR - http://www.scopus.com/inward/record.url?scp=84968754856&partnerID=8YFLogxK

U2 - 10.1016/j.carbon.2016.04.062

DO - 10.1016/j.carbon.2016.04.062

M3 - Article

AN - SCOPUS:84968754856

VL - 106

SP - 93

EP - 105

JO - Carbon

JF - Carbon

SN - 0008-6223

ER -