Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 461-466 |
| Seitenumfang | 6 |
| Fachzeitschrift | Synthesis |
| Ausgabenummer | 3 |
| Publikationsstatus | Veröffentlicht - 11 Jan. 2006 |
Abstract
A convenient one-step transformation of primary and secondary amines into the corresponding unprotected guanidines using 4-benzyl-3,5-dimethyl-1H- pyrazole-1-carboxamidine and its polymer-bound variant is described. The scopes and limitations of the method, the microwave-assistance of amidination as well as a recycling protocol are examined.
ASJC Scopus Sachgebiete
- Chemische Verfahrenstechnik (insg.)
- Katalyse
- Chemie (insg.)
- Organische Chemie
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in: Synthesis, Nr. 3, 11.01.2006, S. 461-466.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Amidination of amines under microwave conditions using recyclable polymer-bound 1H-pyrazole-1-carboxamidine
AU - Solodenko, Wladimir
AU - Bröker, Patrick
AU - Messinger, Josef
AU - Schön, Uwe
AU - Kirschning, Andreas
PY - 2006/1/11
Y1 - 2006/1/11
N2 - A convenient one-step transformation of primary and secondary amines into the corresponding unprotected guanidines using 4-benzyl-3,5-dimethyl-1H- pyrazole-1-carboxamidine and its polymer-bound variant is described. The scopes and limitations of the method, the microwave-assistance of amidination as well as a recycling protocol are examined.
AB - A convenient one-step transformation of primary and secondary amines into the corresponding unprotected guanidines using 4-benzyl-3,5-dimethyl-1H- pyrazole-1-carboxamidine and its polymer-bound variant is described. The scopes and limitations of the method, the microwave-assistance of amidination as well as a recycling protocol are examined.
KW - Amines
KW - Guanidines
KW - Microwave-assisted synthesis
KW - Polymer-bound reagent
KW - Reagent regeneration
UR - http://www.scopus.com/inward/record.url?scp=32644448194&partnerID=8YFLogxK
U2 - 10.1055/s-2006-926284
DO - 10.1055/s-2006-926284
M3 - Article
AN - SCOPUS:32644448194
SP - 461
EP - 466
JO - Synthesis
JF - Synthesis
SN - 0039-7881
IS - 3
ER -