Accelerated deactivation of the boron-oxygen-related recombination centre in crystalline silicon

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OriginalspracheEnglisch
Aufsatznummer095009
FachzeitschriftSemiconductor Science and Technology
Jahrgang26
Ausgabenummer9
PublikationsstatusVeröffentlicht - Sept. 2011
Extern publiziertJa

Abstract

A significant acceleration of the permanent deactivation of the boron-oxygen-related recombination centre in crystalline silicon is observed if the samples are exposed to the plasma during plasma-enhanced chemical vapour deposition (PECVD) of a hydrogen-rich silicon nitride (SiNx) layer. Similar deactivation rate constants are measured in samples passivated with hydrogen-rich SiNx deposited without plasma exposure and hydrogen-lean aluminium oxide (Al2O3) deposited with plasma-assisted atomic layer deposition, suggesting that the critical parameter responsible for the acceleration is not the hydrogen content in the dielectric layer. Instead, we propose increased in-diffusion of hydrogen during or after the deposition of the PECVD SiNx layer, for example due to surface damage caused by plasma exposure, as the cause for the acceleration.

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Accelerated deactivation of the boron-oxygen-related recombination centre in crystalline silicon. / Lim, B.; Bothe, K.; Schmidt, J.
in: Semiconductor Science and Technology, Jahrgang 26, Nr. 9, 095009, 09.2011.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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AU - Bothe, K.

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N2 - A significant acceleration of the permanent deactivation of the boron-oxygen-related recombination centre in crystalline silicon is observed if the samples are exposed to the plasma during plasma-enhanced chemical vapour deposition (PECVD) of a hydrogen-rich silicon nitride (SiNx) layer. Similar deactivation rate constants are measured in samples passivated with hydrogen-rich SiNx deposited without plasma exposure and hydrogen-lean aluminium oxide (Al2O3) deposited with plasma-assisted atomic layer deposition, suggesting that the critical parameter responsible for the acceleration is not the hydrogen content in the dielectric layer. Instead, we propose increased in-diffusion of hydrogen during or after the deposition of the PECVD SiNx layer, for example due to surface damage caused by plasma exposure, as the cause for the acceleration.

AB - A significant acceleration of the permanent deactivation of the boron-oxygen-related recombination centre in crystalline silicon is observed if the samples are exposed to the plasma during plasma-enhanced chemical vapour deposition (PECVD) of a hydrogen-rich silicon nitride (SiNx) layer. Similar deactivation rate constants are measured in samples passivated with hydrogen-rich SiNx deposited without plasma exposure and hydrogen-lean aluminium oxide (Al2O3) deposited with plasma-assisted atomic layer deposition, suggesting that the critical parameter responsible for the acceleration is not the hydrogen content in the dielectric layer. Instead, we propose increased in-diffusion of hydrogen during or after the deposition of the PECVD SiNx layer, for example due to surface damage caused by plasma exposure, as the cause for the acceleration.

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