Absolute cross-sections for the nonresonant multi-photon ionization of toluene and xylene in the gas phase

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Autoren

  • Clemens Walther
  • A. Herlert
  • J. I. Kim
  • Franz J. Scherbaum
  • L. Schweikhard
  • Manuel Vogel

Externe Organisationen

  • Karlsruher Institut für Technologie (KIT)
  • Johannes Gutenberg-Universität Mainz
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)243-250
Seitenumfang8
FachzeitschriftChemical Physics
Jahrgang265
Ausgabenummer2
PublikationsstatusVeröffentlicht - Apr. 2001
Extern publiziertJa

Abstract

The absolute multi-photon ionization cross-section of the phenyl ring was determined by laser-ionization of toluene and xylene molecules in the gas phase. Excitation was achieved using nonresonant four-photon absorption of the frequency doubled light of a 10 ns pulsed Nd:YAG laser (532 nm). The resulting ions were stored in a Penning trap and detected by time-of-flight mass spectrometry. The values of the cross-sections are 1.4(3) × 10-42 cm8W-4s-1 and 1.3(3) × 10-42 cm8W-4s-1 for toluene and xylene, respectively.

ASJC Scopus Sachgebiete

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Absolute cross-sections for the nonresonant multi-photon ionization of toluene and xylene in the gas phase. / Walther, Clemens; Herlert, A.; Kim, J. I. et al.
in: Chemical Physics, Jahrgang 265, Nr. 2, 04.2001, S. 243-250.

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Walther, C, Herlert, A, Kim, JI, Scherbaum, FJ, Schweikhard, L & Vogel, M 2001, 'Absolute cross-sections for the nonresonant multi-photon ionization of toluene and xylene in the gas phase', Chemical Physics, Jg. 265, Nr. 2, S. 243-250. https://doi.org/10.1016/S0301-0104(01)00273-7
Walther, C., Herlert, A., Kim, J. I., Scherbaum, F. J., Schweikhard, L., & Vogel, M. (2001). Absolute cross-sections for the nonresonant multi-photon ionization of toluene and xylene in the gas phase. Chemical Physics, 265(2), 243-250. https://doi.org/10.1016/S0301-0104(01)00273-7
Walther C, Herlert A, Kim JI, Scherbaum FJ, Schweikhard L, Vogel M. Absolute cross-sections for the nonresonant multi-photon ionization of toluene and xylene in the gas phase. Chemical Physics. 2001 Apr;265(2):243-250. doi: 10.1016/S0301-0104(01)00273-7
Walther, Clemens ; Herlert, A. ; Kim, J. I. et al. / Absolute cross-sections for the nonresonant multi-photon ionization of toluene and xylene in the gas phase. in: Chemical Physics. 2001 ; Jahrgang 265, Nr. 2. S. 243-250.
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title = "Absolute cross-sections for the nonresonant multi-photon ionization of toluene and xylene in the gas phase",
abstract = "The absolute multi-photon ionization cross-section of the phenyl ring was determined by laser-ionization of toluene and xylene molecules in the gas phase. Excitation was achieved using nonresonant four-photon absorption of the frequency doubled light of a 10 ns pulsed Nd:YAG laser (532 nm). The resulting ions were stored in a Penning trap and detected by time-of-flight mass spectrometry. The values of the cross-sections are 1.4(3) × 10-42 cm8W-4s-1 and 1.3(3) × 10-42 cm8W-4s-1 for toluene and xylene, respectively.",
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Download

TY - JOUR

T1 - Absolute cross-sections for the nonresonant multi-photon ionization of toluene and xylene in the gas phase

AU - Walther, Clemens

AU - Herlert, A.

AU - Kim, J. I.

AU - Scherbaum, Franz J.

AU - Schweikhard, L.

AU - Vogel, Manuel

N1 - Funding information: This work has been supported by the Materials Science Research Center Mainz, the Fonds der Chemischen Industrie. L.S. thanks the Deutsche Forschungsgemeinschaft for a Heisenberg fellowship.

PY - 2001/4

Y1 - 2001/4

N2 - The absolute multi-photon ionization cross-section of the phenyl ring was determined by laser-ionization of toluene and xylene molecules in the gas phase. Excitation was achieved using nonresonant four-photon absorption of the frequency doubled light of a 10 ns pulsed Nd:YAG laser (532 nm). The resulting ions were stored in a Penning trap and detected by time-of-flight mass spectrometry. The values of the cross-sections are 1.4(3) × 10-42 cm8W-4s-1 and 1.3(3) × 10-42 cm8W-4s-1 for toluene and xylene, respectively.

AB - The absolute multi-photon ionization cross-section of the phenyl ring was determined by laser-ionization of toluene and xylene molecules in the gas phase. Excitation was achieved using nonresonant four-photon absorption of the frequency doubled light of a 10 ns pulsed Nd:YAG laser (532 nm). The resulting ions were stored in a Penning trap and detected by time-of-flight mass spectrometry. The values of the cross-sections are 1.4(3) × 10-42 cm8W-4s-1 and 1.3(3) × 10-42 cm8W-4s-1 for toluene and xylene, respectively.

KW - Multi-photon ionization

KW - Penning trap

KW - Toluene

KW - Xylene

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U2 - 10.1016/S0301-0104(01)00273-7

DO - 10.1016/S0301-0104(01)00273-7

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