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A preliminary assessment of the corrosion behavior of CoCrAlSi alloy as a potential orthopedic implant material

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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OriginalspracheEnglisch
FachzeitschriftJournal of Materials Research
PublikationsstatusElektronisch veröffentlicht (E-Pub) - 2025

Abstract

This study presents the experimental assessment of the corrosion performance of CoCrAlSi alloy in simulated body fluid (SBF) to evaluate its biocorrosion response and potential as an orthopedic implant material. Specifically, the alloy's microstructure was investigated to reveal the elemental segregations and severe segregation zones were identified and analyzed. Static immersion experiments were carried out in SBF in an electronically controlled water bath to examine the ion release behavior of the alloy. The compositions of the surface oxide layers forming upon static immersion were investigated using X-ray photoelectron spectroscopy. Then, potentiodynamic polarization experiments were performed in SBF at 37 °C, which showed that the alloy exhibited a transpassive dissolution behavior, constantly releasing toxic metallic ions. This warrants further elaboration to control the aforementioned ion release mechanism by optimizing the microstructure of CoCrAlSi alloy to evaluate its usability as a potential orthopedic implant.

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A preliminary assessment of the corrosion behavior of CoCrAlSi alloy as a potential orthopedic implant material. / Ozdemir, Huseyin Can; Blank, Tatiana; Gerstein, Gregory et al.
in: Journal of Materials Research, 2025.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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title = "A preliminary assessment of the corrosion behavior of CoCrAlSi alloy as a potential orthopedic implant material",
abstract = "This study presents the experimental assessment of the corrosion performance of CoCrAlSi alloy in simulated body fluid (SBF) to evaluate its biocorrosion response and potential as an orthopedic implant material. Specifically, the alloy's microstructure was investigated to reveal the elemental segregations and severe segregation zones were identified and analyzed. Static immersion experiments were carried out in SBF in an electronically controlled water bath to examine the ion release behavior of the alloy. The compositions of the surface oxide layers forming upon static immersion were investigated using X-ray photoelectron spectroscopy. Then, potentiodynamic polarization experiments were performed in SBF at 37 °C, which showed that the alloy exhibited a transpassive dissolution behavior, constantly releasing toxic metallic ions. This warrants further elaboration to control the aforementioned ion release mechanism by optimizing the microstructure of CoCrAlSi alloy to evaluate its usability as a potential orthopedic implant.",
keywords = "Corrosion, Metal, Passivation, Shape memory, X-ray photoelectron spectroscopy (XPS)",
author = "Ozdemir, {Huseyin Can} and Tatiana Blank and Gregory Gerstein and Demircan Canadinc and Maier, {Hans J{\"u}rgen}",
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TY - JOUR

T1 - A preliminary assessment of the corrosion behavior of CoCrAlSi alloy as a potential orthopedic implant material

AU - Ozdemir, Huseyin Can

AU - Blank, Tatiana

AU - Gerstein, Gregory

AU - Canadinc, Demircan

AU - Maier, Hans Jürgen

N1 - Publisher Copyright: © The Author(s), under exclusive licence to The Materials Research Society 2025.

PY - 2025

Y1 - 2025

N2 - This study presents the experimental assessment of the corrosion performance of CoCrAlSi alloy in simulated body fluid (SBF) to evaluate its biocorrosion response and potential as an orthopedic implant material. Specifically, the alloy's microstructure was investigated to reveal the elemental segregations and severe segregation zones were identified and analyzed. Static immersion experiments were carried out in SBF in an electronically controlled water bath to examine the ion release behavior of the alloy. The compositions of the surface oxide layers forming upon static immersion were investigated using X-ray photoelectron spectroscopy. Then, potentiodynamic polarization experiments were performed in SBF at 37 °C, which showed that the alloy exhibited a transpassive dissolution behavior, constantly releasing toxic metallic ions. This warrants further elaboration to control the aforementioned ion release mechanism by optimizing the microstructure of CoCrAlSi alloy to evaluate its usability as a potential orthopedic implant.

AB - This study presents the experimental assessment of the corrosion performance of CoCrAlSi alloy in simulated body fluid (SBF) to evaluate its biocorrosion response and potential as an orthopedic implant material. Specifically, the alloy's microstructure was investigated to reveal the elemental segregations and severe segregation zones were identified and analyzed. Static immersion experiments were carried out in SBF in an electronically controlled water bath to examine the ion release behavior of the alloy. The compositions of the surface oxide layers forming upon static immersion were investigated using X-ray photoelectron spectroscopy. Then, potentiodynamic polarization experiments were performed in SBF at 37 °C, which showed that the alloy exhibited a transpassive dissolution behavior, constantly releasing toxic metallic ions. This warrants further elaboration to control the aforementioned ion release mechanism by optimizing the microstructure of CoCrAlSi alloy to evaluate its usability as a potential orthopedic implant.

KW - Corrosion

KW - Metal

KW - Passivation

KW - Shape memory

KW - X-ray photoelectron spectroscopy (XPS)

UR - http://www.scopus.com/inward/record.url?scp=85217155792&partnerID=8YFLogxK

U2 - 10.1557/s43578-024-01514-2

DO - 10.1557/s43578-024-01514-2

M3 - Article

JO - Journal of Materials Research

JF - Journal of Materials Research

SN - 0884-2914

ER -

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