A polymer-bound 1,3-diketone: A highly efficient scavenger for hydrazines, and primary amines

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OriginalspracheEnglisch
Seiten (von - bis)983-986
Seitenumfang4
FachzeitschriftSynlett
Ausgabenummer7
PublikationsstatusVeröffentlicht - 20 Mai 2003

Abstract

A 1,3-diketone resin was developed as the basis for a selective scavenger for hydrazines. In addition, it can be employed for the selective removal of primary amines in the presence of secondary amines which is of fundamental importance in the purification of reductive alkylations. The resin's specificity is based on the sequestration of the hydrazine via their polymer-attached pyrazoles and of the primary amines via their enamines.

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A polymer-bound 1,3-diketone: A highly efficient scavenger for hydrazines, and primary amines. / Schön, Uwe; Messinger, Josef; Merayo, Nuria et al.
in: Synlett, Nr. 7, 20.05.2003, S. 983-986.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Schön U, Messinger J, Merayo N, Juszkiewicz G, Kirschning A. A polymer-bound 1,3-diketone: A highly efficient scavenger for hydrazines, and primary amines. Synlett. 2003 Mai 20;(7):983-986. doi: 10.1055/s-2003-39295
Schön, Uwe ; Messinger, Josef ; Merayo, Nuria et al. / A polymer-bound 1,3-diketone : A highly efficient scavenger for hydrazines, and primary amines. in: Synlett. 2003 ; Nr. 7. S. 983-986.
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T2 - A highly efficient scavenger for hydrazines, and primary amines

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AU - Messinger, Josef

AU - Merayo, Nuria

AU - Juszkiewicz, Grzegorz

AU - Kirschning, Andreas

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KW - Combinatorial chemistry

KW - Hydrazines

KW - Polymer supported reagent

KW - Scavenger resin

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