Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 3781-3784 |
| Seitenumfang | 4 |
| Fachzeitschrift | Organic Letters |
| Jahrgang | 2 |
| Ausgabenummer | 24 |
| Publikationsstatus | Veröffentlicht - 10 Nov. 2000 |
Abstract
formula presented A new, polymer-bound reagent system for the efficient oxidation of primary alcohols to aldehydes and secondary alcohols to ketones in the presence of a catalytic amount of 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO) is described. In most cases, workup of this heavy metal-free oxidation is achieved by simple filtration followed by removal of the solvent. In selected examples this reagent was compared with the known polymer-bound permanganate and chromium(VI) reagents.
ASJC Scopus Sachgebiete
- Biochemie, Genetik und Molekularbiologie (insg.)
- Biochemie
- Chemie (insg.)
- Physikalische und Theoretische Chemie
- Chemie (insg.)
- Organische Chemie
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in: Organic Letters, Jahrgang 2, Nr. 24, 10.11.2000, S. 3781-3784.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - A New Polymer-attached Reagent for the Oxidation of Primary and Secondary Alcohols
AU - Sourkouni-Argirusi, Georgia
AU - Kirschning, Andreas
PY - 2000/11/10
Y1 - 2000/11/10
N2 - formula presented A new, polymer-bound reagent system for the efficient oxidation of primary alcohols to aldehydes and secondary alcohols to ketones in the presence of a catalytic amount of 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO) is described. In most cases, workup of this heavy metal-free oxidation is achieved by simple filtration followed by removal of the solvent. In selected examples this reagent was compared with the known polymer-bound permanganate and chromium(VI) reagents.
AB - formula presented A new, polymer-bound reagent system for the efficient oxidation of primary alcohols to aldehydes and secondary alcohols to ketones in the presence of a catalytic amount of 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO) is described. In most cases, workup of this heavy metal-free oxidation is achieved by simple filtration followed by removal of the solvent. In selected examples this reagent was compared with the known polymer-bound permanganate and chromium(VI) reagents.
UR - http://www.scopus.com/inward/record.url?scp=0001520082&partnerID=8YFLogxK
U2 - 10.1021/ol006483t
DO - 10.1021/ol006483t
M3 - Article
AN - SCOPUS:0001520082
VL - 2
SP - 3781
EP - 3784
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 24
ER -