Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 139-145 |
| Seitenumfang | 7 |
| Fachzeitschrift | Journal of membrane science |
| Jahrgang | 567 |
| Publikationsstatus | Veröffentlicht - 1 Dez. 2018 |
| Extern publiziert | Ja |
Abstract
In this work, a novel thin-film composite membrane composed of a polyester film on a cellulose support was successfully synthesised. The polyester film was formed from the interfacial reaction between catechin, a bio-derived poly-phenol, and terephthaloyl chloride (TPC). The cellulose support was prepared by non-solvent induced phase separation from a 12.5 wt% cellulose dope solution in 1-ethyl-3-methylimidazolium acetate ionic liquid. The composite membrane was characterised by Fourier Transform Infrared and X-Ray Photoelectron Spectroscopy to confirm the success of the interfacial reaction. Scanning electron and atomic force microscopy were used to study the surface morphology and roughness of the membranes produced. The performance of the composite membranes in terms of solvent permeance and solute rejection was investigated by studying the rejection of a broad range of different molecular weight dyes in dimethylformamide (DMF) solution. The membranes showed an average DMF permeance of 1.2 L m−2 h−1 bar−1 with a molecular weight cut-off of around 500 g mol−1. The membrane was stable in DMF over 30 days with no significant change in performance. The membrane has potential application in the food and pharmaceutical industries.
ASJC Scopus Sachgebiete
- Biochemie, Genetik und Molekularbiologie (insg.)
- Biochemie
- Werkstoffwissenschaften (insg.)
- Allgemeine Materialwissenschaften
- Chemie (insg.)
- Physikalische und Theoretische Chemie
- Chemische Verfahrenstechnik (insg.)
- Filtration und Separation
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in: Journal of membrane science, Jahrgang 567, 01.12.2018, S. 139-145.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - A catechin/cellulose composite membrane for organic solvent nanofiltration
AU - Abdellah, Mohamed H.
AU - Pérez-Manríquez, Liliana
AU - Puspasari, Tiara
AU - Scholes, Colin A.
AU - Kentish, Sandra E.
AU - Peinemann, Klaus Viktor
N1 - Funding Information: This work was supported by the King Abdullah University of Science and Technology ( KAUST ), Saudi Arabia and the University of Melbourne , Australia.
PY - 2018/12/1
Y1 - 2018/12/1
N2 - In this work, a novel thin-film composite membrane composed of a polyester film on a cellulose support was successfully synthesised. The polyester film was formed from the interfacial reaction between catechin, a bio-derived poly-phenol, and terephthaloyl chloride (TPC). The cellulose support was prepared by non-solvent induced phase separation from a 12.5 wt% cellulose dope solution in 1-ethyl-3-methylimidazolium acetate ionic liquid. The composite membrane was characterised by Fourier Transform Infrared and X-Ray Photoelectron Spectroscopy to confirm the success of the interfacial reaction. Scanning electron and atomic force microscopy were used to study the surface morphology and roughness of the membranes produced. The performance of the composite membranes in terms of solvent permeance and solute rejection was investigated by studying the rejection of a broad range of different molecular weight dyes in dimethylformamide (DMF) solution. The membranes showed an average DMF permeance of 1.2 L m−2 h−1 bar−1 with a molecular weight cut-off of around 500 g mol−1. The membrane was stable in DMF over 30 days with no significant change in performance. The membrane has potential application in the food and pharmaceutical industries.
AB - In this work, a novel thin-film composite membrane composed of a polyester film on a cellulose support was successfully synthesised. The polyester film was formed from the interfacial reaction between catechin, a bio-derived poly-phenol, and terephthaloyl chloride (TPC). The cellulose support was prepared by non-solvent induced phase separation from a 12.5 wt% cellulose dope solution in 1-ethyl-3-methylimidazolium acetate ionic liquid. The composite membrane was characterised by Fourier Transform Infrared and X-Ray Photoelectron Spectroscopy to confirm the success of the interfacial reaction. Scanning electron and atomic force microscopy were used to study the surface morphology and roughness of the membranes produced. The performance of the composite membranes in terms of solvent permeance and solute rejection was investigated by studying the rejection of a broad range of different molecular weight dyes in dimethylformamide (DMF) solution. The membranes showed an average DMF permeance of 1.2 L m−2 h−1 bar−1 with a molecular weight cut-off of around 500 g mol−1. The membrane was stable in DMF over 30 days with no significant change in performance. The membrane has potential application in the food and pharmaceutical industries.
KW - Catechin
KW - Cellulose
KW - Interfacial polymerization
KW - Organic solvent nanofiltration
KW - Polyphenols
UR - http://www.scopus.com/inward/record.url?scp=85053759361&partnerID=8YFLogxK
U2 - 10.1016/j.memsci.2018.09.042
DO - 10.1016/j.memsci.2018.09.042
M3 - Article
AN - SCOPUS:85053759361
VL - 567
SP - 139
EP - 145
JO - Journal of membrane science
JF - Journal of membrane science
SN - 0376-7388
ER -