Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 989-992 |
| Seitenumfang | 4 |
| Fachzeitschrift | Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences |
| Jahrgang | 46 |
| Ausgabenummer | 11 |
| Publikationsstatus | Veröffentlicht - 1 Nov. 1991 |
| Extern publiziert | Ja |
Abstract
Nuclear quadrupole hyperfine structures have been resolved in the rotational spectrum of thionyl aniline, C6H5NSO, using pulsed molecular beam microwave Fourier transform spectroscopy. High precision nuclear quadrupole coupling constants, rotational and quartic centrifugal distortion constants have been determined from the analysis of 12 low-J transitions. Coupling constants are ϰaa= +1.5730(14) MHz and (ϰbb-ϰcc)=—5.6499(13) MHz, rotational constants are A =4026.72i5(4) MHz, B = 860.64732(8) MHz, and C = 709.52027(7) MHz, and centrifugal distortion constants are Δj = 36.6(5) Hz,Δ JK = - 107.5 (20) Hz, ΔK = 703(68) Hz, δj, = 8.1 (5) Hz, and δK= 111 (19) Hz (representation I rused).
ASJC Scopus Sachgebiete
- Mathematik (insg.)
- Mathematische Physik
- Physik und Astronomie (insg.)
- Chemie (insg.)
- Physikalische und Theoretische Chemie
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in: Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, Jahrgang 46, Nr. 11, 01.11.1991, S. 989-992.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - 14N Nuclear Quadrupole Hyperfine Structure in the Rotational Spectrum of Thionyl Aniline
AU - Heineking, N.
AU - Grabow, J. U.
AU - Vormann, K.
AU - Stahl, W.
PY - 1991/11/1
Y1 - 1991/11/1
N2 - Nuclear quadrupole hyperfine structures have been resolved in the rotational spectrum of thionyl aniline, C6H5NSO, using pulsed molecular beam microwave Fourier transform spectroscopy. High precision nuclear quadrupole coupling constants, rotational and quartic centrifugal distortion constants have been determined from the analysis of 12 low-J transitions. Coupling constants are ϰaa= +1.5730(14) MHz and (ϰbb-ϰcc)=—5.6499(13) MHz, rotational constants are A =4026.72i5(4) MHz, B = 860.64732(8) MHz, and C = 709.52027(7) MHz, and centrifugal distortion constants are Δj = 36.6(5) Hz,Δ JK = - 107.5 (20) Hz, ΔK = 703(68) Hz, δj, = 8.1 (5) Hz, and δK= 111 (19) Hz (representation I rused).
AB - Nuclear quadrupole hyperfine structures have been resolved in the rotational spectrum of thionyl aniline, C6H5NSO, using pulsed molecular beam microwave Fourier transform spectroscopy. High precision nuclear quadrupole coupling constants, rotational and quartic centrifugal distortion constants have been determined from the analysis of 12 low-J transitions. Coupling constants are ϰaa= +1.5730(14) MHz and (ϰbb-ϰcc)=—5.6499(13) MHz, rotational constants are A =4026.72i5(4) MHz, B = 860.64732(8) MHz, and C = 709.52027(7) MHz, and centrifugal distortion constants are Δj = 36.6(5) Hz,Δ JK = - 107.5 (20) Hz, ΔK = 703(68) Hz, δj, = 8.1 (5) Hz, and δK= 111 (19) Hz (representation I rused).
UR - http://www.scopus.com/inward/record.url?scp=84915936314&partnerID=8YFLogxK
U2 - 10.1515/zna-1991-1110
DO - 10.1515/zna-1991-1110
M3 - Article
AN - SCOPUS:84915936314
VL - 46
SP - 989
EP - 992
JO - Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences
JF - Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences
SN - 0932-0784
IS - 11
ER -